Introduction of chlorine into aromatic rings by electrophilic substitution is an important synthetic transformation because chlorinated hydrocarbons are recognized as versatile starting materials and additives in th e p rod uctio n o f h igh qu ality in sectic ides, fungicides, herbicides, dyes, pharmaceuticals 1 Moreover, they can serve as precursors for numerous functionalities, such as pheno...

We developed neutral iridium catalysts with chiral spiro phosphine-carboxy ligands (SpiroCAP) for asymmetric hydrogenation of unsaturated carboxylic acids. Different from the cationic Crabtree-type catalysts, the iridium catalysts with chiral spiro phosphine-carboxy ligands are neutral and do not require the use of a tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BArF-) counterion, which is ne...

A novel, solvent-deficient precipitation (SDP) method for catalyst preparation in general and for preparation of iron FT catalysts in particular is reported. Eight catalysts using a 23 factorial design of experiments to identify the key preparation variables were prepared. The catalysts were characterized by electron microprobe, N2 adsorption, TEM, XRD, and ICP. Results show that the morphology...

the mono-metallic and bi-metallic catalysts have been prepared by impregnating with solutions containing a compound of h2ptcl6,wo3 and 1ml hcl (0.1 mol). it should be noted that the catalysts’ activity and selectivity have been determined under these conditions : 450-5000c ,and 15-25atm by h2. for converting n-heptane , the molar ratio h2/c7h16 is 5 , and lhsv is 1.5ml/h. it has been proved tha...

Magnetically recyclable catalysts with magnetic nanoparticles (MNPs) are becoming a major trend towards sustainable catalysts. In this area, recyclable supported ruthenium complexes and ruthenium nanoparticles occupy a key place and present great advantages compared to classic catalysts. In this micro-review, attention is focused on the fabrication of MNP-supported ruthenium catalysts and their...

let  $varpi$ be a representation of the homogeneous space $g/h$, where $g$ be a locally compact group and  $h$ be a compact subgroup of $g$. for  an admissible wavelet $zeta$ for $varpi$  and $psi in l^p(g/h), 1leq p

In this study, the nanoporous γ-alumina catalysts were prepared by the sol-gel method using hydrolysis of aluminum isopropoxide in the presence of TX-100 or gelatin/TX-100 mixture. Catalysts were characterized by XRD, FT-IR, TEM, BET-BJH and N2 adsorption-desorption isotherms. To investigate reactivity and selectivity of the synthesized catalysts, dehydration reaction of 2-octanol was carried o...

Received: 15 December 2004; Revised: 26 January 2005 Abstract Copper zinc oxide catalysts prepared similar to industrially used catalysts were studied by high-resolution electron microscopy. The microstructure of the Cu/ZnO catalysts deviates considerably from that of bulk copper metal and idealized copper model systems. In order to reveal reliable structure-activity relationships for copper ca...