The crystal structure of the intermediate phases in the binary systems of titanium with iron, cobalt, and nickel has been studied and the results compared with those previously published. The phases of the Ti2X type are face-centered cubic with % atoms per cell, and the TiX phases are body-centered cubic. TiFe, and Tic02 are hexagonal but not isomorphous. The nickel-rich phase has the compositi...

We report on the synthesis of nanostructured and crystalline tapered Si and Ge polyhedra via metal-catalyzed chemical vapor deposition. These Si and Ge nanocones (SiNCs, GeNCs) possess tips with near-atomic sharpness, micron-scaled bases, hexagonal cross-sections, and controllable apex angles. High-resolution transmission electron microscopy, selected-area electron diffraction and Raman scatter...

The electronic structure of YMnO3 in its highand low-temperature hexagonal phases has been investigated within the local spin-density approximation (LSDA) and by the LSDA + U method which takes into account the local Coulomb interaction between d electrons of transitionmetal ions. In contrast to the case for orthorhombic manganites, the d4-configuration degeneracy is already lifted in the high-...

In our present work undoped CdS and Cu doped CdS thin films were deposited on glass substrate by chemical bath method. XRD analysis of the as-prepared sample indicated CdS:Cu nanorods to be mixture of two phases namely hexagonal and cubic. It has been observed that one particular plane (100) has preferentially grown as the maximum intense peak whereas the other two planes (101) and (102) have d...

Growth of CdS was studied in three different liquid crystalline phases demonstrating the versatility of liquid crystal templating of inorganic solids. Semiconductor growth in a hexagonal liquid crystal yielded a nanostructure with hexagonal symmetry, a lamellar liquid crystal yielded a lamellar nanostructure, and a cubic liquid crystal (consisting of spherical micelles) yielded a hollow, spheri...

Freezing of a Lennard-Jones fluid between solid surfaces was studied using grand canonical Monte Carlo and molecular dynamics simulations. We explored the formation of frozen phases of hexagonal and orthorhombic symmetry in mono-, bi-, and tri-layer structures. The freezing transition, the type of lattice, and translational and orientational ordering were identified on the basis of orientationa...

Amorphous Ge₂Sb₂Te₅ (GST) alloy, upon heating crystallize to a metastable NaCl structure around 150°C and then to a stable hexagonal structure at high temperatures (≥250°C). It has been generally understood that the phase change takes place between amorphous and the metastable NaCl structure and not between the amorphous and the stable hexagonal phase. In the present work, it is observed that t...