The effect of clay and chemical cross-linking on the dynamic mechanical properties polyurethane reinforced with different concentrations organically modified montmorillonite is investigated in this study. matrix constituted polytetrahydrofuran soft segment 4,4′-methylenebis(phenyl isocyanate) hard segment. Glycerin was used as crosslinking agent, while Cloisite 30B reinforcing filler. nanocompo...

Objective The aim of the present study was to evaluate the mechanical and thermal characteristics of two denture base acrylic resins containing silver nanoparticles (AgNPs). Material and Methods Two different acrylic denture base resins (heat-polymerized and microwave polymerized) containing 0.3, 0.8 and 1.6 wt% AgNPs were evaluated for flexural strength, elastic modulus and impact strength. ...

The effect of various humidities on process yields and degrees of crystallinity for spray-dried powders from spray drying of lactose with humid air in a straight-through system have been studied. It has been suggested by Williams–Landel–Ferry kinetics (WLF) that a higher particle temperature and lower glass-transition temperature would increase the crystallization rate of the particles during t...

Modulated differential scanning calorimetry, wide angle x-ray scattering, and environmental scanning electron microscopy were used to investigate the physical and morphological properties of chicory root inulin spray dried under different conditions. When the feed temperature increased up to 80 °C, the average degree of polymerization of the solubilized fraction increased, leading to a higher g...

The effective thermal and dynamic properties of composites containing polymethyl-metha-acralyte (PMMA) dispersed with single-wall carbon nanotubes (SWCNTs) were studied by modulation/ac calorimetry (ACC) and modulation-differential-scanning (MDSC) calorimetric techniques. The specific heat and effective thermal conductivity were determined by ACC from 300 to 400 K as a function of SWCNT content...

The glassy states of water are of common interest as the majority of H2O in space is in the glassy state and especially because a proper description of this phenomenon is considered to be the key to our understanding why liquid water shows exceptional properties, different from all other liquids. The occurrence of water's calorimetric glass transition of low-density amorphous ice at 136 K has b...

Acryloyl based novel energetic monomers having nitro acrylates and nitro triazole acrylates were synthesized and further used for polymerization. Due to scavanging properties of nitro groups, syntheses of nitro aromatic polymers are not facile at normal conditions. In this regard, we report a simple protocol to synthesize these energetic group embeded acroloyl polymers. These polymers were char...

This work involves the development of a novel siliconized epoxy interpenetrating coating system using epoxy resin as base, hydroxylterminated polydimethylsiloxane (HTPDMS) as modifier, -aminopropyltriethoxysilane ( -APS) as crosslinking agent and dibutyltindilaurate (DBTDL) as catalyst. Polyamidoamine and aromatic polyamine adduct were used as curing agents for the above coating systems. The th...

In the electronics industry epoxy molding compounds, underfills and adhesives are used for the packaging of electronic components. These materials are applied in liquid form, cured at elevated temperatures and then cooled down to room temperature. During these processing steps residual stresses are built up resulting from both cure and thermal shrinkage. These residual stresses add up to the st...

Thin polymer films have attracted attention because of both their broad range of applications and of the fundamental questions they raise regarding the dynamic response of confined polymers. These films are unstable if the temperature is above their glass transition temperature Tg. Here, we describe freestanding thin films of centimetric dimensions made of a comb copolymer melt far from its gla...