Silica-supported oxovanadium groups were reacted in a gas-solid reaction with aniline at 175 degrees C. The reaction was clean as monitored in situ by UV-vis spectroscopy and resulted in the elimination of water as the principal product of the reaction and the disappearance of the terminal V=O stretch in the Raman spectrum. 15N MAS solid-state NMR spectroscopy showed only a single nitrogen-cont...

This manuscript demonstrates the design, modification and initial investigation of a rotary furnace for the manufacturing of inorganic fullerene WS2 nanoparticles. Different preparation methods starting with various precursors have been investigated, of which the gas-solid reaction starting with WO3 nanoparticles was the most efficient technique. Furthermore, the influence of temperature, react...

Heat transfer phenomena in batch fluidized bed dryer have been studied and analyzed using three phase model including solid phase, interstitial gas phase and bubble phase based on Rizzi model. New correlations of heat transfer coefficient to surrounding and convection heat transfer coefficient between solid and interstitial gas are being proposed. In addition, some modifications have been d...

Biofiltration of air polluted by volatile organic compounds is now recognized by the industrial and research communities as an effective and viable alternative to standard environmental technologies. Whereas many studies have focused on solid/liquid/gas biofilters, there have been fewer reports on waste air treatment using other biological processes, especially in a solid/gas biofilter. In this...

Both solid to gas (CaSO< + SiO — CaSi03 + S02 and Si3N4 + 3C (diamond) —» and 3SiC -f 2 N^) can be shock-induced at ballistic velocities. Because of the endothermic nature of the gas-producing reactions, the extent of reactions observed are limited to interfaces. We found the above reactions proceed to a much less extent than calculation by equilibrium thermodynainic calculations. Reaction prod...

A two fluid model (TFM) was used to study gas-solid heat transfer in a riser with different inclination angles. A two dimensional pipe with 5.8 cm internal diameter and 5 meter length was chosen.  Effect of bed angle and solid particles feed rate were studied on the heat transfer behavior of gas and solid particles. Obtained results from simulation are compared with the experimental data in the...

background and objectives: the addition of plasticizers (mainly phthalates and adipates) makes plastic flexible and popular for packaging, storing and preserving food, water, and so on. the most widely used plasticizer in food contact applications is di-ethylhexyl phthalate (dehp) though being suspected to have carcinogenic and estrogenic properties. the aim of this study is application of magn...

carbon disulfide is used predominantly in the manufacture. it has affects the nervous system. in this study, the applicability of spme as a passive sampler for determination of carbon disulphide in air was studied. effect of sampler and environmental parameters on uptake of carbon disulphide was studied as well. four fibers were tested to select the best sampler for determine carbon disulfide i...