The importance of solid-state diffusion and crystal growth of the solid product in a gas-solid reaction with solid product formation (GSRSPF) are discussed with direct sulfation of limestone as a representative example. A GSRSPF usually involves nucleation and crystal growth of the solid product, which are necessary processes for the formation of the new phase of the solid product. Solid-state ...

A model has been developed that can account for both front and back "autodoping" effects during epitaxial growth as well as impurity redistribution during further high-temperature processing. The model incorporates three dopant fluxes, i.e., (i) the flux from the solid into the gas phase at the rear of the wafer, (ii) the flux from the solid to the front surface of the wafer, and (iii) the flux...

The fabrication of flexible, stretchable and rechargeable devices with a high energy density is critical for next-generation electronics. Herein, fiber-shaped Zn-air batteries, are realized for the first time by designing aligned, cross-stacked and porous carbon nanotube sheets simultaneously that behave as a gas diffusion layer, a catalyst layer, and a current collector. The combined remarkabl...

Flexible and transparent gas-diffusion barriers have played an important role in recent years. The present study describes a flexible barrier film with a tailored architecture of cationic polyelectrolytes and clay/polymer nanoassemblies. Highly oriented and well-aligned barrier films were achieved by the consecutive absorption of flexible cationic polymer and anionic montmorillonite platelets. ...

To approach this goal, we develop a detailed 1D model to describe the DMFC on the electrode and cell level, based on the in-house modeling framework DENIS. A two-phase flow model is implemented for the transport in gas diffusion layer (GDL) and catalyst layer (CL) at the anode side, whereas we consider only the gas phase at the cathode side. Electrochemistry is described by multistep mechanisms...