The transition to alternative fuels and vehicles presents many challenges that require long-range strategic thought and planning. Fuel producers must make expensive infrastructure decisions about which fuels to support years before they are sold. Vehicle producers must commit to new drivetrains on a similar long-range schedule. Whichever technologies prevail, hydrogen fuel cell, PHEV, BEV or bi...

This study combines theory and experiment to determine the kinetically relevant steps and site requirements for deoxygenation of alkanols and alkanals. These reactants deoxygenate predominantly via decarbonylation (C-C cleavage) instead of C-O hydrogenolysis on Ir, Pt, and Ru, leading to strong inhibition effects by chemisorbed CO (CO*). C-C cleavage occurs via unsaturated species formed in seq...

Microkinetics simulations are presented on the intrinsic activity and selectivity of the Fischer-Tropsch reaction with respect to the formation of long chain oxygenated hydrocarbons. Two different chain growth mechanisms are compared: the carbide chain growth mechanism and the CO insertion chain growth mechanism. The microkinetics simulations are based on quantum-chemical data on reaction rate ...

reduction of exhaust emissions is a major research task in diesel engine development in view of increasing concerns regarding environmental protection and stringent exhaust gas regulations. simultaneousreduction of nox emissions and particulate matter is quite difficult due to the soot/nox trade-off and isoften accompanied by fuel consumption penalties. towards this aim, automotive engineers ha...