An optically active polyaniline nanomaterial (PANI-Nap), doped with (S)-naproxen, was developed and evaluated as a potent pH sensor. We synthesized the material in one pot by the addition of the dopant, (S)-naproxen, prior to polymerization, followed by the addition of the oxidizing agent (ammonium persulfate) that causes polymerization of the aniline. This green chemistry approach allowed us t...

Nowadays, the use of lasers and other biospectroscopic techniques such as Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR), Mass, UV-Vis, FT-Raman, 1HNMR, 13CNMR and 31PNMR spectroscopies have had significant progress in treatment of cancer diseases [1-17]. Process of irradiation transmission and absorption in human cells’ tissues is very important in diagnosis an...

Senile graying of human hair has been the subject of intense research since ancient times. Reactive oxygen species have been implicated in hair follicle melanocyte apoptosis and DNA damage. Here we show for the first time by FT-Raman spectroscopy in vivo that human gray/white scalp hair shafts accumulate hydrogen peroxide (H(2)O(2)) in millimolar concentrations. Moreover, we demonstrate almost ...

In this research zinc oxide (ZnO) nano-crystalline powders were prepared by sol-gel method using zinc acetate. The ZnO nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), ultraviolet-visible (UV-Vis), Fourier transform infra-red (FT-IR) and energy dispersive X-ray (EDX) spectroscopy. The structure of nanoparticles was studied using XRD pattern. The c...

FT-Raman spectroscopy (FT-RS) was used to investigate green tea’s potential protective effect as an antioxidant during frozen storage of Atlantic mackerel (Scomber scombrus). stored for more than 26 weeks at −10°C or –80°C (control), with without tea (GT). Raman analysis showed substantial changes in protein structure due storage, especially the higher temperature (−10°C), compared findings −80...

We report the preparation of highly ordered mesoporous Fe-Al-SBA-15 with isolated extraframework Fe species under acidic conditions. The materials were characterized by means of UV resonance Raman spectroscopy, in conjunction with BET, XRD, TEM, UV-vis, H2-TPR, FT-IR, and 27Al MAS NMR spectroscopy. The addition of both Fe and Al to the synthesis gel of SBA-15 results in the formation of isolate...

This chapter covers the fundamental principles and current applications of Fourier transform (FT) infrared and Fourier transform Raman spectroscopies as utilized in the analysis of polymeric materials. The primary emphasis of the first part is on the principles and advantages of these interferometric methods, whereas the remaining sections illustrate numerous applications focusing on the struct...

Cr2O3 nanoparticles were prepared using Cr(NO3)3.9H2O as starting material, triethanolamine (TEA) as template and water as green solvent under microwave irradiation. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR), photoluminescence (PL) and Raman spectroscopy. The size distribution of individual particles we...

bioactive materials including glass and glass-ceramics are nowadays used as medical implants for orthopedic applications. in this study several samples of glass-ceramics have been prepared using both heat treatment and sol-gel processes. the structure and bioactivity of these samples based on their interaction with simulated body fluid (sbf) have been determined. in-vitor, using the raman spect...