Pyridinium based ionic liquids derived from β-picoline and n-alkylbromides were synthesized by a simple procedure at ambient temperature and then characterized. These neutral ionic liquids were investigated for their dual role as the solvent and promoter for the selective synthesis of a series of N-monomethylanilines using dimethylcarbonate as the methylating agent. A solvent free gree...

the treatment equimolar quantities of carboxylic acids with acid chlorides in the presence of zno brings abouthighly efficient unsymmetrical anhydrides at room temperature in solvent-free condition. reactivity trendsfavored formation of the product using both electron deficient and rich aryl acids and acid chlorides.

sulfonic acid functionalized sba-15 as a nanoporous acid catalyst was used in the synthesis of 2-aryl benzoxazoles 4 by the condensation of 2-aminophenol 1 and benzoyl chlorides 2 under microwave irradiation in solvent free reaction conditions. the advantages of this methodology are good product yields (60-98%), being environmentally benign, short reaction times and easy work up.

Modeling and optimization of synthesis gas production via the non-catalytic partial oxidation of methane (NCPO) were studied by minimizing of Gibbs free energy, and comparison studies were carried out to analyze the mechanism of syngas production. For this purpose, concentrations of CO2 and H2O in the feed were optimized in specified pressure and temperature, such that the hydrogen to carbon mo...

In order to determination of ileum apparent and true digestibility of two samples of poultry by product meal, an experiment was conducted with a total of 60 day-old broiler chicks, Ross 308 strain. Poultry by-product meal was prepared from two slaughter house in Alborz province. Samples were sent to laboratory for determination of chemical analysis. The birds received commercial broiler starter...

We prove that the free Fock space F(R + ; C), which is very commonly used in Free Probability Theory, is the continuous free product of copies of the space C 2. We describe an explicit embedding and approximation of this continuous free product structure by means of a discrete-time approximation: the free toy Fock space, a countable free product of copies of C 2. We show that the basic creation...

We prove that the free Fock space F(R+;C), which is very commonly used in Free Probability Theory, is the continuous free product of copies of the space C2. We describe an explicit embeding and approximation of this continuous free product structure by means of a discrete-time approximation: the free toy Fock space, a countable free product of copies of C2. We show that the basic creation, anni...

Sulfonic acid functionalized SBA-15 as a nanoporous acid catalyst was used in the synthesis of 2-Aryl benzoxazoles 4 by the condensation of 2-aminophenol 1 and benzoyl chlorides 2 under microwave irradiation in solvent free reaction conditions. The advantages of this methodology are good product yields (60-98%), being environmentally benign, short reaction times and easy work up.