Rhombohedral single crystallites of hematite (iron oxide, R-Fe2O3) in the size range of 20-200 nm have been synthesized by forced hydrolysis in water. The optical Rayleigh scattering and AFM topography of individual crystallites have been recorded on an inverted microscope based apparatus. Individual crystallites show narrow Mie “optical cavity” resonances across the visible spectrum as the par...

Nanocrystalline ZnO particles were prepared from ethanolic solutions of zinc acetate by forced hydrolysis, at a low temperature. The fresh prepared ZnO nanoparticles were coated with gentamicin. The nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and thermal analysis (TG-DSC). The electronic (UV-Vis), infrared (FTIR) and photoluminescence (PL)...

The stability-indicating LC assay method was developed and validated for quantitative determination of cefpirome sulfate (CPS) in the presence of degradation products formed during the forced degradation studies. An isocratic HPLC method was developed with Lichrospher RP-18 column, 5 μm particle size, 125 mm x 4 mm column and 12 mM ammonium acetate-acetonitrile (90 : 10 v/v) as a mobile phase. ...

moderate to excellent entantio- and stereoselectivities (ee’s 54-100%) were observed in ple catalyzed hydrolysis of (±)-ethyl 5-oxo-endo-tricyclo[5.2.1.02,6] deca-8-ene-2-carboxylate 5 and the structurally related open chain bicyclic structures (±)-ethyl 3-acetylbicyclo[2.2.1]hept-5-ene-2-carboxylates 7, 9 and (±)-ethyl 3-propanoylbicyclo[2.2.1]hept-5-ene-2-carboxylates 8, 10. a pronounced pref...

acrylic-type polymeric systems having degradable ester bonds linked to ibuprofen were synthesized and evaluated as materials for drug delivery. ibuprofen, as a non-steroidal anti-inflammatory drug, was linked to 2-hydroxyethyl methacrylate by activated ester methodology in one-pot procedure. the resulting methacrylic derivative of ibuprofen was copolymerized with 2-hydroxyethyl methacrylate and...

Methods for determination of bisoprolol and related substances mostly use UV detection a phosphate buffer are not suitable MS detection. In this study, LC?UV?MS/MS separation characterization was developed, validated applied studying the degradation products when exposed to hydrolytic stress, heat light. The method uses C18 column, formic acid in water acetonitrile as mobile phases, gradient el...

mnco2o4 (mno-co2o3) nanocomposite as a binary oxide has been successfully prepared by precipitation method using cobalt nitrate and manganese nitrate as the precursors and then characterized by scanning electron microscopy-energy dispersive micro-analysis (sem-edx) and x-ray diffraction (xrd) techniques. in this work, we report the hydrolysis kinetics reactions of semi mustard (chloroethyl ethy...

We study spatial localization in the real subcritical Ginzburg-Landau equation ut = m0u + Q(x)u + uxx + d|u|u − |u|u with spatially periodic forcing Q(x). When d > 0 and Q ≡ 0 this equation exhibits bistability between the trivial state u = 0 and a homogeneous nontrivial state u = u0 with stationary localized structures which accumulate at the Maxwell pointm0 = −3d/16. When spatial forcing is i...