Phosphorus-based flame retardants were incorporated into different, easily preparable matrices, such as polymeric thermoset resins and paraffin as a proposed model for polyolefins and investigated for their flame retardancy performance. The favored mode of action of each flame retardant was identified in each respective system and at each respective concentration. Thermogravimetric analysis was...

Edge flames were investigated in a methane/O2/N2 counterflow diffusion flame burner. In a typical experiment, a stable counterflow diffusion flame in an axysymmetric configuration was perturbed by lowering the relevant Damköhler number slightly below the extinction value, Daext. As a result, the flame extinguished in the vicinity of the burner axis where conditions were uniform. An edge flame e...

We consider generalized flame balls which correspond to stationary spherical flames with a flow of hot inert gas, either a source or a sink, at the origin. Depending on the flow, these flames can have positive, zero, or negative burning speeds, with zero speeds characterizing the Zeldovich flame balls. A full analytical description of these structures and their stability to radial perturbations...

The general objective of this project is to support the development and validation of large eddy simulation (LES) models used to simulate the response of fires to the activation of suppression systems. The focus here is on suppression by gaseous agents. The present experimental configuration is a two-dimensional, plane, buoyancydriven, methane-fueled, turbulent diffusion flame with a controlled...

The present study experimentally investigates fundamental characteristics of diffusion flames and the importance of gas radiation. In particular, transient measurements of flame growth, temperature, and radiation intensity of an expanding spherical diffusion flame in microgravity are used to investigate the effects of various diluents (N2, CO2) with different radiative properties. Two systems w...

This paper presents experimental investigations of the in situ diagnosis of the alkali metals in the municipal solid waste (MSW) flame of an industrial grade incinerator using flame emission spectroscopy. The spectral radiation intensities of the MSW flame were obtained using a spectrometer. A linear polynomial fitting method is proposed to uncouple the continuous spectrum and the characteristi...

With the phase-out of PentaBDE in 2004, alternative flame retardants are being used in polyurethane foam to meet flammability standards. However, insufficient information is available on the identity of the flame retardants currently in use. Baby products containing polyurethane foam must meet California state furniture flammability standards, which likely affects the use of flame retardants in...