A rapid, sensitive and accurate atomic absorption method for Cr(III) and Cr(VI) ions was developed based on the cloud-point extraction (CPE) technique. Cr(III) reacts with a new Schiff's base ligand to form the hydrophobic complex, which is subsequently entrapped in the surfactant micelles. The Cr(VI) assay is based on its reduction to Cr(III) by the addition of concentrated H2SO4 and ethanol t...

The purpose of this study was to determine tissue concentration toxic metals, namely Mn, Cr, Ni, Cu, Fe, Cd, Pb, and Zn, in the removed third molars patients from Legnica-Głogów copper district. A group 69 with an average age 27.3 ± 6.9 years enrolled into study. There were 16 (23.2%) men 53 (76.8%) women. Patients divided two groups according place residence—residents Copper Area (n = 49) cont...

This work describes a method to determine Cu at wide range concentrations in a single run without need of further dilutions employing high-resolution continuum source flame atomic absorption spectrometry. Different atomic lines for Cu at 324.754 nm, 327.396 nm, 222.570 nm, 249.215 nm and 224.426 nm were evaluated and main figures of merit established. Absorbance measurements at 324.754 nm, 249....

a novel, magnetic silica sorbent with polyelectrolyte multilayers (pems) on its surface was prepared, and was used for magnetic solid phase extraction (mspe) of trace a+ via flame atomic absorption spectrometry (faas). the experimental parameters for the mspe procedure, such as the ph, type, and concentration of eluent, ultrasonic time and effects of co-existing ions were investigated. the dete...

objective: the aim of this study was to find out the prevalence of hypozincemia in patients suffering from tinnitus and to investigate the effect of zinc therapy upon the severity of tinnitus. material and methods: we studied 66 who suffered from tinnitus, which were randomized to two groups according to the zinc level including < 50μg/dl and > 50μg /dl groups. the zinc level was measured in no...

Some heavy metals are dangerous to health and there is rising concern about the quality of foodstuffs in some parts of the world. Fish, particularly Tuna fish, can concentrate huge quantities of several metals from water and they even play a significant role in human nourishment. OBJECTIVES: In this study, the concentrations of mercury and four trace metals in five brands of canned tuna samples...

A non-flame atomizer incorporating a graphite tube and cup is used to determine lead in whole blood and packed erythrocytes. In a direct method, a 2-mu-l sample is treated in situ in the cup with 1 mu-l of concentrated nitric acid. The oxidized sample can then be dried, ashed, and atomized without leaving a residue. The nitric acid treatment obviates correction for nonselective absorption, some...

SYNOPSIS The free and total plasma copper and total erythrocyte copper levels have been determined by simple, yet sensitive and highly specific methods, using atomic absorption spectrophotometry. For total copper determination, the copper was split from its protein combination in plasma or red cells by the action of hydrochloric acid at room temperature. The liberated copper was chelated by amm...