Locations of Cu2+ ion in Cu(2+)-adsorbed montmorillonite have been studied by electron paramagnetic resonance (EPR), supplemented by X-ray diffraction (XRD) and differential thermal analysis (DTA). In the EPR spectra of Cu(2+)-adsorbed montmorillonite, three signals, corresponding to Cu2+ ion, have been simultaneously recorded. Some Cu2+ ions seemed to replace the original interlayer metal cati...

Fruit tree shoots are potential useful resources that rich in carbohydrates and inorganic nutrients but not typically utilized sustainable agriculture. Our objective was to evaluate the soil properties quality of an orchard after returning apple situ investigate contribution rate as exogenous source organic carbon for fertility amendment root domain. One-year-old were pruned spring before buddi...

The tropical forests of the Amazon Basin occur on a wide variety of different soil types reflecting a rich diversity of geologic origins and geomorphic processes. We here review the existing literature about the main soil groups of Amazonia, describing their genesis, geographical patterns and principal chemical, physical and morphologic characteristics. Original data is also presented, with pro...

— The crystal structure of K2TiSi3O9•H2O has been solved ab initio from X-ray powder data. The unit cell is orthorhombic (space group P212121, Z = 4) with cell dimensions a = 7.1362(2) Å, b = 9.9084(3) Å, c = 12.9414(4) Å, V = 915.07 Å. The structural model was obtained from direct methods using 455 integrated intensities. The Rietveld refinement converged to final Bragg and profile indicators ...

By controlling the extent of hydrolysis during the self-assembly process of a zwitterionic-based ligand with uranyl cations, we observed a structural evolution from the neutral uranyl-organic framework [(UO2)2(TTTPC)(OH)O(COOH)]·1.5DMF·7H2O (SCU-6) to the first cationic uranyl-organic framework with the formula of [(UO2)(HTTTPC)(OH)]Br·1.5DMF·4H2O (SCU-7). The crystal structures of SCU-6 and SC...

The interactions of clay minerals with organic compounds which give rise to the formation of colored complexes, are discussed. The color reactions of clays can be ascribed to a charge transfer between the mineral and the adsorbed species. The active sites on the clay are aluminums exposed at crystal edges and/or transition metal cations in the higher valency state at planar surfaces both of whi...

Septic tank effluent is inherently high in sodium ions relative to divalent cations (high sodium adsorption ratio). The disposal of septic tank effluent to the soil will cause the sodium ions to disperse the clay colloids, resulting in a physical blocking of the soil pores. Hydraulic conductivity will be reduced and the effluent will fail to dissipate into the soil profile. In designing the dis...

Physicochemical and ionic characteristics of groundwater aquifers have been tremendous importance in water applications. Groundwater selected coastal communities (Badagry, Epe, Ikorodu, Ilaje/ese-odo) south-western Nigeria was assessed for domestic irrigation suitability. One hundred ninety-two (192) samples were obtained analyzed chemical composition major ratio over a period four seasons usin...

Besides having a large capacity for taking up organic molecules, clay minerals can catalyze a variety of organic reactions. Derived from rock weathering, clay minerals would have been abundant in the early Earth. As such, they might be expected to play a role in chemical evolution. The interactions of clay minerals with biopolymers, including RNA, have been the subject of many investigations. T...