The Graz Cycle, a hydrogen oxygen fired double loop high temperature steam cycle, combining gas turbine philosophy with steam plant praxis, can be adapted for combustion of methane with oxygen. The resulting combustion products carbon dioxide and hydrogen oxide, i.e. high temperature steam, are mixed with cooling steam and expanded to lowest pressure and temperature. By condensing the steam, se...

The CO2 reforming of coke oven gas for the production of synthesis gas has been studied over an activated carbon, an in-lab prepared Ni/Al2O3 catalyst and physical mixtures of both materials in different proportions (AC+Ni) at 800 oC. It was found that there are two possible coexisting reaction pathways: the direct dry reforming of methane (decomposition of methane followed by gasification of t...

In this work, a reliable kinetic reaction mechanism was revised to accurately reproduce the detailed paths of steam reforming methane over Ni/Al2O3 catalyst. A steady-state fixed-bed reactor experiment and 1D catalyst model were utilized for task. The distinctive feature is possibility measure axially resolved temperature profile bed, which makes kinetics inside visible. This allows understandi...

Growing grassland biomass in an extensive way and its subsequent transformation into hay for a further utilization in a biogas-based biorefinery concept could be a solution to increase incomes and maintain the grassland area. In this way, gassland can be promising biomass sources for decentralized energy generation. Efficient biogas production from this lignocellulosic biomass requires a pretre...

A combined catalyst and sorbent was prepared and utilized for steam reforming methane and propane in laboratory-scale systems. The material was prepared in the form of small spherical pellets having a layered structure such that each pellet consisted of a highly reactive lime or dolime core enclosed within a porous but strong protective shell made of alumina in which a nickel catalyst was loade...

Grass is generally considered as one of the major agricultural products and covers over 90% of Irish agricultural land. While useful as an animal feedstock it can also be used for energy production. Here batch mesophilic anaerobic digestion of grass silage was studied. The methane concentration in the biogas clearly showed that grass silage has a high affinity to produce a high quality methane ...