The effect of the working electrode surface must be considered in this type of study, since it is thought to strongly influence the kinetics of relaxation [1]. The ESCR model was developed based on experimental data obtained from PPy films deposited on polished Pt. In those (anion-transporting) systems, nucleation was observed in the form of expanding cylinders that coalesced over time (visible...

Supramolecular soft-templating approaches to mesoporous materials have revolutionized the generation of regular nanoarchitectures exhibiting unique features such as uniform pore structure with tunable dimensions, large surface area, and high volume, variability composition, and/or ease functionalization a wide range organo-functional groups or good hosts for in situ synthesis nano-objects. One ...

A range of novel multilayer films were fabricated onto ITO-coated glass through the electrochemical polymerization (MEP) technology using three EDOT-based electrochromic polymers (P1, P2 and P3) with additive primary colors red, green blue (RGB) respectively in neutral state, high transmissivity oxidized state. As expected, a highly desired black-to-transmissive switching low driving voltages (...

Abstract Intensive development of nanofabrication processes has opened a new window to control electromagnetic waves using subwavelength nanostructures array, named metasurfaces. Although the metasurfaces have succeeded in achieving unprecedented functionality by arranging various shapes modulate properties incident light, inherent passive characteristics make it impossible alter engraved funct...

In nature, some organisms have the ability to camouflage adapt environmental changes; they blend with environment by changing their skin colors. Such a phenomenon is of great significance for research adaptive materials. this study, we propose novel design scheme study angle-independent photonic materials and successfully prepare an electrically tunable multi-color display inverse opal gel (IOP...

This review provides detailed information on the synthesis, structure, properties, methods for studying, and areas of application conductive polymers synthesized basis phenylenediamines. Conductive based phenylenediamines are cationic salts highly conjugated by electrochemical or chemical oxidation. Chemical oxidative polymerization has led to formation various functional polymers. Depending re...

Four bis-tridentate ruthenium complexes with 5,5′′-divinyl-4′-tolyl-2,2′:6′,2′′-terpyridine (dvtpy) have been synthesized. Among them, 3(PF6) ([(dvtpy)Ru(Mebib)](PF6)) and 4(PF6) ([(dvtpy)Ru(dpb)](PF6)) are cyclometalated, and 5(PF6)2 ([(dvtpy)Ru(Mebip)](PF6)2) and 6(PF6)2 ([(dvtpy)Ru(tpy)](PF6)2) are noncyclometalated, where Mebib is 2-deprotonated-1,3-bis(N-methylbenzimidazolyl)benzene, dpb i...