Layered double hydroxides (LDHs), luminescent π-conjugated anionic polymer and montmorillonite (MMT) were orderly assembled into luminescent multilayer films via layer-by-layer self-assembly method. The electronic microenvironment (EME), the structure of which is like a traditional capacitor, can be constructed by exfoliated LDHs or MMT nanosheets. In addition, the rigid inorganic laminated con...