Controlling crystal orientations and macroscopic morphology is vital to develop the electronic properties of hybrid perovskites. Here we show that a large-area, orientationally pure crystalline (OPC) methylammonium lead iodide (MAPbI3) hybrid perovskite film can be fabricated using a thermal-gradient-assisted directional crystallization method that relies on the sharp liquid-to-solid transition...

Directed migration by contact guidance is a poorly understood yet vital phenomenon, particularly for carcinoma cell invasion on aligned collagen fibres. We demonstrate that for single cells, aligned architectures providing contact guidance cues induce constrained focal adhesion maturation and associated F-actin alignment, consequently orchestrating anisotropic traction stresses that drive cell ...

Routing in infrastructure less vehicular ad hoc networks is challenging because of the dynamic network, predictable topology, high speed of nodes, and predictable mobility patterns. This paper presents an enhanced routing protocol specifically designed for city environments. It uses vehicular speed and directional density for dynamic junction selection. Simulation results exhibit increased pack...

We mapped spatially varying intramolecular electronic structures on a pentacene-gold interface using scanning tunneling spectroscopy. Along with ab initio calculations based on density functional theory, we found that the directional nature of the d orbitals of Au atoms plays an important role in the interaction at the pentacene-gold contact. The gold-induced interface states are broadened and ...

Hydraulic systems, as power sources and transmissions, offer many advantages over electromechanical or purely mechanical counterparts in terms of power density, flexibility, and portability. Many hydraulic systems require touching and contacting the physical environments; and many of these systems are directly controlled by humans. If hydraulic systems are passive, they would be both safer to i...

Coverage is a prominent indicator for measuring the quality of service in directional sensor networks. From perspective energy and deployment costs, full coverage may be expensive or unrealistic, partial can operate more energy-efficient by scheduling working status sensors. In certain practical application scenarios, irregular obstacles like trees, mountains, buildings, vehicles, which have ad...

Traditional topic models do not account for semantic regularities in language. Recent distributional representations of words exhibit semantic consistency over directional metrics such as cosine similarity. However, neither categorical nor Gaussian observational distributions used in existing topic models are appropriate to leverage such correlations. In this paper, we propose to use the von Mi...

We report accurate ab initio theoretical predictions of the elastic, seismic, and structural anisotropy of the orthorhombic Mg2SiO4 forsterite crystal at high pressures (up to 20 GPa) and temperatures (up to its melting point, 2163 K), which constitute earth's upper mantle conditions. Single-crystal elastic stiffness constants are evaluated up to 20 GPa and their first- and second-order pressur...

Variables and constraints in problem domains are often distributed. These distributed constraint satisfaction problems (DCSPs) lend themselves to multiagent solutions. Most existing algorithms for DCSPs are extensions of centralized backtracking or iterative improvement with breakout. Their worst case complexity is exponential. On the other hand, directional consistency based algorithms solve c...

We demonstrate that the emission of light by fluorescent molecules in the proximity of periodic arrays of nanoantennas or plasmonic crystals can be strongly modified when the arrays are covered by a dielectric film. The coupling between localized surface plasmon resonances and photonic states leads to surface modes which increase the density of optical states and improve light extraction. Excit...