Direct methanol fuel cells (DMFCs) are considered to be one of the most promising candidates for portable and stationary applications in the view of their advantages such as high energy density, easy manipulation, high efficiency and they operate with liquid fuel which could be used without requiring any fuel-processing units. Electrolyte membrane of DMFC plays a key role as a proton conductor ...

Direct-methanol fuel cell (DMFC) systems are comparatively simple, sometimes just requiring a cartridge and stack with appropriate control devices. The key challenge in these is the accurate determination of flow rates mixture methanol water, fundamental understanding can be gained by computational fluid dynamics. In this work, three-dimensional, steady-state, two-phase, multi-component non-iso...

The development of a durable and methanol tolerant electrocatalyst with a high oxygen reduction reaction activity is highly important for the cathode side of direct methanol fuel cells. Here, we describe a simple and novel methodology to fabricate a practically applicable electrocatalyst with a high methanol tolerance based on poly[2,2'-(2,6-pyridine)-5,5'-bibenzimidazole]-wrapped multi-walled ...

Dimethyl ether (DME) has been considered as a promising alternative fuel for direct-feed fuel cells but lack of an efficient DME oxidation electrocatalyst has remained the challenge for the commercialization of the direct DME fuel cell. The commonly studied binary PtRu catalyst shows much lower activity in DME than methanol oxidation. In this work, guided by density functional theory (DFT) calc...

A porous ceramic support is designed as a multi-functional independent catalyst layer for solid oxide fuel cells (SOFCs) running on liquid hydrocarbon fuel. The consists of highly Ce0.9Ca0.1O2?? backbone and active NiMo catalysts, which could be integrated into the conventional Ni metal containing anode internal reforming Compared to layers sintered anode...

Carbon capsules with hollow core and mesoporous shell (HCMS) structures were used as a support material for Pt(50)-Ru(50) catalyst, and the catalytic performance of the HCMS supported catalyst in the direct methanol fuel cell was described; the HCMS carbon supported catalysts exhibited much higher specific activity for methanol oxidation than the commonly used E-TEK catalyst by about 80%, provi...

In this study, TiO2 nanotubes (TNTs) were synthesized via a hydrothermal method using highly concentrated NaOH solutions varying from 6 to 12 M at 180 °C for 48 h. The effects of the NaOH concentration and the TNT crystal structure on the performance for methanol oxidation were investigated to determine the best catalyst support for Pt-based catalysts. The results showed that TNTs produced with...

This paper reviews the chemical and electrochemical depositions of platinum group metals (PGMs) from aqueous solutions. With a brief introduction on the fundamental aspects of chemical/electrochemical depositions, the review describes recent advances in chemical and Abbreviations: CD, cathode current density expressed as amperes per cm2; CE, cathode current efficiency; dc, direct current; DMFC,...