Mordenite (H-MOR) catalysts were synthesized by a hydrothermal method, and silver-modified mordenite (Ag-MOR) prepared ion exchange with AgNO3 at different concentrations. The performance of these in the carbonylation dimethyl ether (DME) to methyl acetate (MA) was also evaluated. characterized Ar adsorption/desorption, XRD, ICP-AES, SEM, HRTEM, 27Al NMR, H2-TPR, NH3-TPD, Py-IR, CO-TPD. Accordi...

The diethyl ether extract of the Japanese liverwort Metacalypogeia cordifolia yielded five new chroman type derivatives in addition to known sesquiterpenoids. One of the new chroman derivatives was also isolated from the ether extract of another liverwort, Cephalozia otaruensis. Their structures were established by extensive two dimensional (2D) NMR techniques and chemical evidence. They were s...

The synthesis and application of dimethyl carbonate (DMC) are achieving increasing importance due to its low toxicity and versatile reactivity. DMC can be used as environmentfriendly intermediate and starting material for organic synthesis via carbonylation and it can replace methylating agents such as dimethyl sulphate and methyl halides [1–3]. DMC is also being considered as a component for r...

The reaction of dimethyl-amine hydro-chloride, 18-crown-6 and ferric chloride in ethanol yields the title compound, (C(2)H(8)N)[FeCl(4)]·C(12)H(24)O(6), which exhibits an unusual supramolecular structure. The protonated dimethyl-amine contains one NH(2) (+) group, resulting in a 1:1 supra-molecular rotator-stator structure (CH(3)-NH(2) (+)-CH(3))(18-crown-6), through N-H⋯O hydrogen-bonding inte...