In this paper, an effective numerical method is introduced for the treatment of nonlinear two-dimensional Volterra-Fredholm integro-differential equations. Here, we use the so-called two-dimensional block-pulse functions.First, the two-dimensional block-pulse operational matrix of integration and differentiation has been presented. Then, by using this matrices, the nonlinear two-dimensional Vol...

UNLABELLED The aim of this work was to develop a selective method for quantification of Sn(II) and Sn(IV) in dimercaptosuccinic acid (DMSA), ethylcysteinate dimer (ECD), methylenediphosphonic acid (MDP), and pyrophosphate radiopharmaceutical cold kits by differential pulse polarography. METHODS A dripping mercury electrode 150 polarographic/stripping analyzer with a conventional 3-electrode c...

A selective, sensitive, rapid and simple-handling analytical method for the determination of cyanide at low detection limits in surface and underground water, soil and industrial waste samples was developed. The method is based on a reaction, proposed by Guilbault and Kramer, where free cyanide reacts with p-nitrobenzaldehyde to form an intermediate cyanohydrin, which reacts with o-dinitrobenze...

An extremely sensitive pulse polarographic method for the determination of zinc dimethyldithiocarbamate (an agricultural fungicide) and zinc di-n-pentyldithiocarbamate (a petroleum additive), has been developed based on the reaction of their dithiocarbamate moiety with copper(II) perchlorate in acetonitrile medium. Well defined diffusion-controlled peaks are observed at –140 mV and –130 mV (vs ...

Absence of gradients and Nernstian equilibrium stripping (AGNES) is an emerging electroanalytical technique designed to measure free metal ion concentration. The practical implementation of AGNES requires a critical selection of the deposition time, which can be drastically reduced if the contribution of the complexes is properly taken into account. The resin titration (RT) is a competition met...

the adsorptive behavior of the immunosuppressive agent tacrolimus was studied by cyclic and differential-pulse voltammetry on a hanging mercury drop electrode (hmde). the drug was accumulated at hmde and two well-defined peak currents were obtained at -1353 and -1417 mv vs . sce (saturated kcl) in borate buffer (ph 10.0) + 0.1 kcl solution. a voltammetric procedure was developed for the determi...

Dionýz Ilkovič (Figure 1) was a Czechoslovak physicist and physical chemist. He made fundamental contributions to the theoretical background of polarography electroanalytical chemistry in general. Polarography is first technique that performs voltammetric study with mercury-dropping electrode 2A). This invented 1922 by Czech chemist Jaroslav Heyrovský, who received Nobel prize 1959 for inventio...