the adsorption of 2-mercaptobenzimidazole (2-mbi) on au(111) has been studied withcyclic voltammetry (cv), in-situ subtractively normalised interfacial ft-ir spectroscopy (sniftirs)and scanning tunnelling microscopy (stm). although adsorbed 2-mbi reduces the interfacial capacityand quenches the characteristic features of the cyclic voltammogram for sulfate adsorption,heterogeneous electron tran...

glassy carbon (gc) is the most commonly used carbon-based electrode in the analytical laboratory. because of the high background current and low electrode response, modification of this electrode can be done by various materials and techniques. an ionic liquid (il), 1-methyl-3-(3-trimethoxysilyl propyl) imidazoliumbis (trifluoromethylsulfonyl) imide, was covalently cross linked onto the gc surf...

the combination of graphene and nickel oxide nanoparticles yields nanostructured electrochemical sensor formed a novel kind of structurally uniform and electrocatalytic activity material. in cyclic voltammetry studies, in the presence of epinephrine, nickel oxide / graphene  composite modified electrode shows a significantly higher current response for epinephrine oxidation. based on differenti...

Cyclic voltammetry is a fundamental experimental method for characterizing electrochemical surfaces. Despite its wide use, a way to quantitatively and directly relate cyclic voltammetry to ab initio calculations has been lacking. We derive the cyclic voltammogram for H on Pt(111) and Pt(100), based solely on density functional theory calculations and standard molecular tables. By relating the g...

A novel electrochemical sensor was proposed for the determination of amitriptyline based on the copper oxide (CuO) nanoparticles modified graphite screen-printed electrode. CuO nanoparticles were used to enhance the surface area of the electrode and then improve the sensitivity of the electrochemical sensor. Amitriptyline electrochemical response characteristics of the modified electrode in a p...

A novel electrochemical sensor was proposed for the determination of amitriptyline based on the copper oxide (CuO) nanoparticles modified graphite screen-printed electrode. CuO nanoparticles were used to enhance the surface area of the electrode and then improve the sensitivity of the electrochemical sensor. Amitriptyline electrochemical response characteristics of the modified electrode in a p...

Both the short- and long-term electron-transfer processes of electrode-respiring Geobacter sulfurreducens biofilms are demonstrated by using an electrochemical quartz crystal microbalance (QCM). The QCM monitors the frequency shift from the initial resonant frequency (background) in real time, while the current increases, because of biofilm growth. In the short term, the frequency shift is line...

In this paper, phenol was determined in a liquid solution based on fabricating phenol-selective electrode by cyclic voltammetry (CV). The carbon paste modified with nickel oxide nanoparticles (NiO) which were doped nitrogen quantum dots (NCQD) as the NiO-NCQD nanocomposite. manufactured laboratory at optimized pH. condition, best results created pH 7.0 and 4.0 using KH2PO4 buffer solution. By v...

There are various ways to impose a potential variation in time, and subsequently a series of voltammetric methods. Cyclic voltammetry relies on linearly scanning the potential in time, observing a triangular waveform variation [1-3]. Differential pulse voltammetry is based on two samplings of the current intensity for each potential pulse: one measurement before applying the pulse, and the seco...

This paper describes a stripping method for the determination of nevirapine at the submicromolar concentration levels. The method is based on controlled adsorptive accumulation of nevirapine at thin-film mercury electrode, followed by a linear cyclic scan voltammetry measurement of the surface species. Optimal experimental conditions include a 2.0 x 10(-3) mol L(-1) NaOH solution (supporting el...