Reaction of a phosphane-decorated benzenedithiol (pbdtH2) with coinage metal salts furnished polynuclear complexes [M2(pbdtH)2] (M=AuI) or [cat][M5(pbdt)3] (cat=unipositive cation, M=AgI, CuI), which were characterized by analytical and spectroscopic techniques single-crystal X-ray diffraction studies. Furthermore, double salt an anion [Ag5(pbdt)3(PPh3)]− that proved unstable in solution was cr...

Use of a substituted digermylene oxide as a ligand has been demonstrated through the isolation of a series of group 11 metal(I) iodide complexes. Accordingly, the reactions of digermylene oxide [{(i-Bu)2ATIGe}2O] (ATI = aminotroponiminate) (1) with CuI under different conditions afforded [({(i-Bu)2ATIGe}2O)2(Cu4I4)] (2) with a Cu4I4 octahedral core, [({(i-Bu)2ATIGe}2O)2(Cu3I3)] (3) with a Cu3I3...

A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4'-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2':6',2''-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4'-(4-bromophenyl)-2,2':6',2''-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interan...

Dr. Z. Chen, Dr. C. Wang, J. Lopez, Prof. Z. Bao Department of Chemical Engineering Stanford University Stanford , CA 94305 , USA E-mail: [email protected] Dr. Z. Lu, Prof. Y. Cui Department of Materials Science and Engineering Stanford University Stanford , CA 94305 , USA E-mail: [email protected] Prof. Y. Cui Stanford Institute for Materials and Energy Sciences SLAC National Accelerator Labo...

The Cu(I)-catalyzed N,N'-diarylation of natural diamines and polyamines such as putrescine, cadaverine, spermine, spermidine and their homologues is described. Aryl iodides bearing electron-donating and electron-withdrawing groups have been employed in the study. The CuI/2-(isobutyryl)cyclohexanone/DMF catalytic system has found to be more efficient in the diarylation of diamines and spermine w...

R. Y. Wang, Dr. M. Pasta, Dr. H.-W. Lee, Prof. Y. Cui Department of Materials Science and Engineering Stanford University Stanford , CA 94305 , USA E-mail: [email protected] Dr. B. Shyam, Dr. K. H. Stone, Dr. J. N. Weker, Dr. M. F. Toney Stanford Synchrotron Radiation Lightsource SLAC National Accelerator Laboratory Menlo Park , CA 94025 , USA Prof. Y. Cui Stanford Institute for Materials and ...

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Oscillator strengths and lifetimes of all energy levels of CuI, Agl and AuI were calculated using the Coulomb approximation (for The first time), and then compared with available data

In recentyears,attentionhasbeendirected to theconcept of the Perioperative Surgical Home (PSH). The origin of this concept can be attributed to the introductionof ambulatory surgery and the riseofpreadmission testing centers, which led to improvements in the preoperative recognition and management of risk factors and a reduction in the use of preoperative screening services and tests that provi...

The reaction of copper(I) iodide with N-acetyl-thio-morpholine (L, C6H11NOS) in aceto-nitrile results in a coordination polymer with composition [CuI(L)2] n . The CuI atom is coordinated by two S atoms and two I atoms, adopting a distorted tetra-hedral environment. The μ2-bridging mode of the I atoms gives rise to chains extending parallel to [010]. C-H⋯O hydrogen-bonding inter-actions between ...