As the electrochemical method, the Fast Fourier Transform (FFT) Stripping Cyclic Voltammetry detection method was designed for measurement and monitoring of adsorbed mercury ions by new modified adsorbent based on mesoporous silica as a new adsorbent. In this respect, SBA-15 as mesoporous silica and 1, 3, 5 Trithiane as effective modifier ligand were chosen, and the modification process was car...

keep in mind the importance of cadmium, cobalt and nickel ions as environmentally and economically strategic heavy metals, the application of two acidic extractants, named bis(2-diethylhexyl)phosphoric acid (dehpa) and 2-thenoyltrifluoroacetone (htta), was assessed for the extraction-recovery of these ions from leached solution of spent rechargeable ni-cd batteries. the conditions for leaching ...

The current study was attributed to uranium (VI) ions adsorption using a anion exchanger resin, Dowex®2x8, in the presence of sulfate anions. Evaluation of operational parameters including contact time, pH, initial concentration of uranium ions, and presence of various anions (including phosphate, sulfate, chloride, fluoride, and nitrate) in the solution was assessed on sorption performance of ...

In this article, theoretical studies on the selective complexation of the halide ions (F¯, Cl¯ and Br¯) and ion pairs (Na+F¯, Na+Cl¯ and Na+Br¯) with the cyclic nano-hexapeptide (CP) composed of L-proline have been performed in the gas phase. In order to calculate the dispersion interaction energies of the CP and ions, DFT-D3 calculations at the M05-2X-D3/6-31G(d) level was employed. Based on t...

In this study, the blast furnace slag was used as absorbing bed and then, its ionic adsorption was studied. For this reason, various experimental parameters such as pH, contact time and the primary ion concentration were investigated. The remaining concentrations of ions such as; Mn2+ and Fe2+ in water were measured by atomic adsorption spectroscopy. The chemical and p...

   In this study, cadmium sulfide nanoparticles (CdS NPs) were prepared, characterized and used as a new adsorbent for simultaneous removal of Pb(II) and Cu(II) ions from aqueous solutions. Using a batch adsorption method, the effects of solution pH, contact time, adsorbent dose, and temperature were studied and optimized. Removal efficiencies, higher than 98% were obtained for both the met...

Magnetic chitosan nanocomposites are one of the more recent advanced groups of adsorbents used to remove contaminants from waste water. In this research, N- Nicotinyl-N', N"-bis (Hexamethylenyl) phosphoric triamide (HE) was used as an additive to form a new nanocomposite with the structure of chitosan / 5% Fe3O4 Nps/10% HE resulting in the highly efficient removal of Cd(II...

Ethylene glycol bisthioglycolate modified gold nanoparticles grafted Mn doped Fe3O4 nanoparticles (Au@Mn-Fe3O4 NPs) adsorbent was synthesized and applied for extraction and preconcentration of trace amounts of Ag+ and Pb2+ ions in artificial and natural saliva. The adsorbent was characterized by transmission electron microscopy (...

Co-precipitation procedure was applied in order to obtain different kinds of magnetic nanoadsobents for the removal of Pb(II) and Cu(II) toxic metal ions from wastewater samples. Prepared nanoadsorbents were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometer (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The average sizes of t...

Abstract A new adsorbent, ethylene glycol bisthioglycolate modified gold nanoparticles grafted Mn doped Fe3O4 nanoparticles (EGBTG-Au@Mn-Fe3O4 NPs) were synthesized through chemical precipitation followed by an oxidative Mn doping process to use for extraction and preconcentration of trace amounts of Hg, and Cu ions in artificial and natural saliva. The prepared adsorbent was characterize...