نتایج جستجو برای: coordination polymers
تعداد نتایج: 146597 فیلتر نتایج به سال:
The solvothermal in situ double cycloaddition reaction of 2-cyanopyrimidine, Cu(2)O and NaN(3) with aqueous ammonia additive generated a two dimensional copper(I) coordination polymer with 5-pyrimidyl-tetrazolate, 3,5-bispyrimidyl-1,2,4-triazolate and the cyano group as the ligands. This reaction can be tuned to yield two dimensional coordination polymers solely based on tetrazolate or 1,2,4-tr...
Three isomeric water-soluble and light-stable silver(I) coordination polymers with a fluorinated carboxylate ligand were prepared by template-controlled method, which show different 2D polymeric coordination structures with a novel layered inorganic connectivity in the solid state. In water solution, they dissociate into several stable polynuclear silver(I) oligomers and exhibit extraordinary a...
A simple and straightforward synthesis of a new linear trinuclear Cu(I) cluster with polyphosphine ligands is presented. The reaction of this pre-organized Cu3 precursor with En ligand complexes (E = P, As; n = 2, 5) affords discrete complexes exhibiting end-on η(1)-coordination of the E2 ligands or one-dimensional coordination polymers featuring σ-1,3-bridging E5 rings, respectively.
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