mold powders in continuous casting of steel contain fluorine through mainly caf2 and occasionally naf andna3alf6. fluorine develops dangerous gases such as sif4 and hf at high temperatures. in this study, caf2 is partly replaced by substances such as na2co3, zno and fe2o3.sulfur free portland cement clinker containing gypsum was used as a new product base. these additions developed comparable v...
