State Key Laboratory of Catalysis, iChEM Chinese Academy of Sciences, Dalian 1160 [email protected] University of Chinese Academy of Sciences, Department of Physics, Arizona State Unive State Key Laboratory of Coal Conversion Academy of Sciences, Taiyuan 030001, Chin † Electronic supplementary information material characterization data, and cat 10.1039/c7sc00568g ‡ These authors contributed e...

We investigate a new class of ternary materials such as LiAuSe and KHgSb with a honeycomb structure in Au-Se and Hg-Sb layers. We demonstrate the band inversion in these materials similar to HgTe, which is a strong precondition for existence of the topological surface states. In contrast with graphene, these materials exhibit strong spin-orbit coupling and a small direct band gap at the Γ point...

Particles from channelled emissions of a battery recycling facility were size-segregated and investigated to correlate their speciation and morphology with their transfer towards lettuce. Microculture experiments carried out with various calcareous soils spiked with micronic and sub-micronic particles (1650+/-20mg Pb kg(-1)) highlighted a greater transfer in soils mixed with the finest particle...

A copper-catalyzed radical 1,2-aryl migration in α,α-diaryl allylic alcohols is developed, leading to β-silyl carbonyl compounds in moderate to good yields. The migration of aryls with lower aromaticity is favored. This procedure features the employment of silanes as commercially available materials.

General homogeneous conditions for the palladium-catalyzed synthesis of carbonyl compounds with tertiary carbon stereocenters at the alpha-position are reported. The highly reactive catalyst tolerates a variety of substrate substitution and functionality, and generates enantioenriched cyclic ketones from racemic allyl beta-ketoester starting materials.

By choosing V-shaped ligands, Cu2+ cations and isopolymolybdates as starting materials, a novel double helical compound [Cu(H2O)(bimb)]2[β-Mo8O26] (1) (bimb = 1,3-bis(1-imidazoly)benzene) was hydrothermally synthesized and characterized by elemental analyses, single-crystal X-ray diffraction, powder X-ray diffraction and IR spectroscopy. A structural feature is that compound 1 represents the fi...

Had the great American philosopher Yogi Berra been a condensed matter physicist, he might have said “It’s difficult to make predictions, especially about superconductivity.” Predictions about a material’s structure and even more so its function have been goals of materials research for a long time, but the track record for predicting that a given compound will superconduct is notoriously bad [1...

*Correspondence: Muhammad Rizwan Saleem, Center for Energy Systems (CES), USAID Center for Advance Studies, National University of Sciences and Technology (NUST), Sector H-12, Islamabad 44000, Pakistan e-mail: [email protected]; [email protected] We review the significance of optical thin films by Atomic Layer Deposition (ALD) method to fabricate nanophotonic devices and structures. A...

The novel discovery of a current-induced transition from insulator to metal in the crystalline phase of Ge2Sb2Te5 and GeSb4Te7 have been studied by means of a model using line-patterned samples. The resistivity of cubic phase Ge-Sb-Te compound was reduced by an electrical current (~1 MA/cm(2)), and the final resistivity was determined based on the stress current density, regardless of the initi...