Herein we present a new approach for the complete removal of Cr(VI) species, through reduction of Cr(VI) to Cr(III), followed by adsorption of Cr(III). Reduction of chromium from water is an important challenge, as Cr(IV) is one of the most toxic substances emitted from industrial processes. Chitosan (CS) thin films were developed on plain polysulfone (PSf) and PSf/TiO2 membrane substrates by a...

INTRODUCTION Hexavalent chromium, Cr(VI), is the most toxic form of the metal chromium, a primary drinking water contaminant in the U.S. Dissolved hexavalent chromium can be determined as chromate (CrO 4 ) by ion chromatography in drinking water, groundwater, and industrial wastewater effluents as described in U.S. EPA Method 218.6 and Dionex Technical Note 26. Dionex Technical Note 26 uses a 2...

Here we report the results of dissociative electron attachment (DEA) to gas-phase chromium(0) hexacarbonyl (Cr(CO)6) and benzene-chromium(0) tricarbonyl ((η6-C6H6)Cr(CO)3) in the energy range of 0-12 eV. Measurements have been performed utilizing an electron-molecular crossed beam setup. It was found that DEA to Cr(CO)6 results (under the given experimental conditions) in the formation of three...

Thionitrosyl Complexes, Nit rosy 1 Chromium Complexes A nitromethane solution of NS+PFe-, obtained in situ from N3S3CI3 and AgPF6 (1:3), reacts with benzene tricarbonyl chromium in acetonitrile solution to give the thionitrosylcontaining salt [Cr(NS)(NC-Me)s](PF6)2 (1)In the presence of Zerf-butyl isocyanide and Zn powder, 1 is reduced to [Cr(NS)(CN-CMe3)s]PF6 (3), while subsequent oxidation of...

Effects of water contamination with perchlorate and hexavalent chromium [Cr (VI)] on the mosquito Culex quinquefasciatus were assessed. The chronic (10-day) LC50s values for perchlorate and chromium were 74+/-8.0 mg/L and 0.41+/-0.15 mg/L, respectively. Relative Growth Index, a measure of growth and mortality rates in a population, was significantly reduced within 5 days for levels of perchlora...

OBJECTIVE Chromium has gained popularity as a nutritional supplement for diabetic patients. This study evaluated the effect of chronic administration of a chromium complex of D-phenylalanine (Cr(D-phe)(3)) on glucose and insulin tolerance in obese mice. The study tested the hypothesis that Cr(D-phe)(3) suppresses endoplasmic reticulum (ER) stress and insulin resistance in these animals. METHO...

OBJECTIVES Chromium VI (hexavalent chromium, Cr(VI)) is an established cause of lung cancer, but its association with gastrointestinal cancer is less clear. The goal of this study was to examine whether the current human epidemiological research on occupationally inhaled Cr(VI) supports the hypothesis that Cr(VI) is associated with human stomach cancer. METHODS Following a thorough literature...

A lab experiment was conducted to evaluate the effect of chromium (Cr) on seed germination, root elongation and coleoptile growth in pigeon pea (Cajanus cajan). The seed of the pigeon pea was treated with five concentrations of Cr (0, 20, 40, 80 and 100 ppm). The results indicated that the per cent germination of test crop was decreased after application of 20 ppm Cr concentration. The effect o...

EXTENDED ABSTRACT Hexavalent chromium [Cr(VI)] has long been recognized as a potential carcinogen, via the inhalation route while nowadays, there is an increasing concern that Cr(VI) is also carcinogenic by the oral route of exposure. According to this, governments apply more stringent regulations for chromium species. There are several discussions and intentions to lower the current maximum pe...