In the first part of this work, correlation between optical activity and elements of magnetic susceptibility tensor (MST) for five classes of model small molecules containing a single chiral center has been studied using quantum computational techniques at DFT-B3LYP level of theory with 6-311G basis set. Several molecular properties are used to reduce the MST elements prior to the examination o...

A new generalized high-frequency transmission line model is presented for general uniform hybrid waveguide structures consisting of inhomogeneous isotropic or anisotropic media. Starting from Maxwell's equations, the generalized coupled telegrapher's equations are found and the frequency-dependent transmission line parameter matrices R(~o), G(w), L(c0), and C(w) are defined in an unambiguous wa...

   In chiral and non-chiral electrophoretic resolution of basic drugs, adsorption of analytes to negatively charged capillary wall could lead to poor repeatability of migration time and peak area. In addition, chiral resolutions of basic drugs are commonly performed in low pH buffers. Therefore, longer analysis time due to suppression of electroosmotic flow (EOF) is another dilemma. In this wor...

The presence of chirality in the main molecules of life may well be not just a structural artifact, but of pure biological advantage. The possibility of the existence of a phenomenon of a special mode of interaction, labeled as " chiral interaction " (CI), for which structural chirality is a necessary condition , is the main reason for such an advantage. In order to demonstrate such a possibili...

The paper addresses the two-point correlations of electromagnetic waves in general random, bi-anisotropic media whose constitutive tensors are complex Hermitian, positiveor negative-definite matrices. A simplified version of the two-frequency Wigner distribution (2f-WD) for polarized waves is introduced and the closed form Wigner-Moyal equation is derived from the Maxwell equations. In the weak...

The paper addresses the two-point correlations of electromagnetic waves in general random, bi-anisotropic media whose constitutive tensors are complex Hermitian, positiveor negative-definite matrices. A simplified version of the two-frequency Wigner distribution (2f-WD) for polarized waves is introduced and the closed form Wigner–Moyal equation is derived from the Maxwell equations. In the weak...

(-)-gephyrotoxin-223 was formally synthesized from chiral synthon 1 which has been chemoenzymatically synthesized  in the presence  of candida antartica lipase.

Recently, bianisotropic media again received increasing importance in electromagnetic theory because of advances in material science which enable the manufacturing of complex bianisotropic materials. By using Maxwell's equations and corresponding boundary conditions, the electromagnetic field distribution in bianisotropic solenoid coils is determined and the influence of the bianisotropic behav...

Strecker reaction is one of the simplest multicomponent reactions. It used for synthesis of chiral α-amino nitriles. This reaction was carried out in the presence of catalytic amount of layered double hydroxides (LDHs). In this study, simple and practical method for the synthesis of this class of catalysts is provided. The results shown that LDH is the good heterogen catalyst for synthesis of c...