IR-transparent chalcogenide glass-ceramics were fabricated through a careful ceramization process of the as-prepared 65GeS2 25Ga2S3 10LiI glasses at a temperature of 403 1C for various durations. Owing to the precipitation of LixGaySz crystals with a Ga2S3-like structure, clear second-harmonic generation was observed in the sample crystallized at 403 1C for 60 h, which has a greatly improved re...

We studied cation exchange (CE) in core/shell Cu2-xSe/Cu2-xS nanorods with two cations, Ag(+) and Hg(2+), which are known to induce rapid exchange within metal chalcogenide nanocrystals (NCs) at room temperature. At the initial stage of the reaction, the guest ions diffused through the Cu2-xS shell and reached the Cu2-xSe core, replacing first Cu(+) ions within the latter region. These experime...

Photoluminescence (PL) and excitation spectra of Bi melt-doped oxide and chalcogenide glasses are very similar, indicating the same Bi center is present. When implanted with Bi, chalcogenide, phosphate and silica glasses, and BaF2 crystals, all display characteristically different PL spectra to when Bi is incorporated by melt-doping. This indicates that ion implantation is able to generate Bi c...

A low temperature Monte Carlo dynamics of a Keating-like oscillator model is used to study the relationship between the nature of network glasses from the viewpoint of rigidity, the thermal reversibility during the glass transition and the strong-fragile behaviour of glass-forming liquids. The model shows that a Phillips optimal glass formation with minimal enthalpic changes is obtained under a...

The energetic χ-criterion is developed to parameterize difference in the origin of high-order optical non-linearity associated with metallic atoms (Cu, Ag, Au) embedded destructively in oxide- and chalcogenide glasses. Within this approach, it is unambiguously proved that covalent-bonded networks of soft semiconductor chalcogenides exemplified by binary As(Ge)-S(Se) glasses differ essentially f...

We study bend loss in chalcogenide negative curvature fibers with different polarizations, different tube wall thicknesses, and different bend directions relative to the mode polarization. The coupling between the core mode and tube modes induces bend loss peaks in the two non-degenerate modes at the same bend radius. There is as much as a factor of 28 difference between the losses of the two p...