نتایج جستجو برای: cerium iv oxide
تعداد نتایج: 355035 فیلتر نتایج به سال:
Ferroelectric field effect transistors (FeFETs) have attracted much attention recently because of their ability to combine high speed, low power consumption, and fast nondestructive readout with the potential for high density nonvolatile memory. The polarization of the ferroelectric is used to switch the channel at the silicon surface between states of high and low conductance. Among the ferroe...
A Quartz Crystal Microbalance (QCM) Study of Single-Strand DNA Hybridization and Hydrolytic Cleavage
The use of a quartz crystal microbalance (QCM) for monitorin g in situ the immobilization of singlestrand DNA marked with mercaptol group at the 5'-end on the surface of a gold-filled 7.995 MHz AT-cut quartz crystal by Au–S bond with the self-assembly technique is reported. The hybridization of ssDNA with complementary 10-mer ODN and 8-mer ODN is described. The QCM was also employed to analyze ...
For the first time electron spin resonance (ESR) spectroscopic technique has been used for a highly selective determination of chlorpromazine. The method is based on the oxidation reaction of chlorpromazine with cerium(IV) in sulfuric acid media. In this method 3.8x10(-3) mol dm(-3) cerium(IV) was used in 0.035 mol dm(-3) sulfuric acid with the ESR spectra recorded at room temperature. A calibr...
The oxidation of alcohols, n-propanol, 2-methoxy ethanol and 2-ethoxy by cerium (IV) in nitric acid leads to the formation corresponding aldehydes. reaction is first order with respect Ce(IV). A Michaelis-Menten type kinetics observed alcohols. retarded initial [Ce(IV)] increase concentration oxidant. exhibits participation 2 mole 1 It has been concluded that Ce(IV)-dimer participate process fr...
The objective of this study is to develop a simple, environmentally benign alternate analytical method for simultaneous estimation of iron oxidation states. This proposed method of iron speciation is based on 1,10-phenanthroline (phen) modified redox potential of transition metal ions. In a pre-step excess cerium(IV) oxidizes iron(II) in sample to iron(III). Initial back titration of un-reacted...
A series of montmorillonite-(Ce or Zr) phosphate crosslinked compounds has been synthesized by reaction of a cerium or zirconium cation exchanged montmorillonite (diameter ~2 pm) with phosphoric acid under appropriate conditions of concentration, addition rate and temperature. The materials thus obtained were characterized by chemical and thermal analyses, X-ray diffraction, IR spectroscopy and...
The trivalent compound K[Ce[N(SiHMe2)2]4] was synthesized and oxidized, providing a convenient route to the reported cerium(IV) compound Ce[N(SiHMe2)2]4. Protonolysis reactions of Ce[N(SiHMe2)2]4 with tert-butanol, substituted benzyl alcohols, and 2,6-diphenylphenol yielded the neutral tetravalent compounds Ce(O(t)Bu)4(py)2, Ce2(OCH2C6R5)8(thf)2 (R = Me, F), and Ce(Odpp)4 (dpp = 2,6-(C6H5)2-C6H...
As an alternative to chromate conversion coatings, rare-earth coatings especially cerium, because of the low toxicity, have attracted considerable attention. Using dip immersion method, cerium-based conversion coating was deposited on aluminum 2024. Corrosion resistance was studied in 3.5 wt.% NaCl solution using potentiodynamic polarization, electrochemical impedance spectroscopy, and surface ...
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