In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O at...

The coexistence of Down syndrome (DS) and celiac disease (CD) has been reported in many studies. In our study, we examined 82 children with DS aged 8 months to 8.6 years for the existence of CD using serological markers immunoglobulin A (IgA) and immunoglobulin G (IgG) transglutaminase antibodies, followed by follow-up determination of total IgA levels. In four children who were positive for on...

The spectral properties of Bowman-Birk soybean trypsin inhibitor (BBI) were investigated by analyzing difference absorption spectra and difference CD spectra and by comparing them with those of tyrosyl model compounds. The O-acetylation of tyrosyl side chains showed that the ultraviolet CD bands of BBI above 225 nm originate from disulfide side chains and tyrosyl phenolic groups; phenylalanyl r...

The Cd(II) atom in the title compound, [CdCl(2)(C(10)H(8)N(2))(2)] exists in a distorted octa-hedral geometry [N-Cd-N = 148.29 (17)°]; the Cl atoms are cis with respect to each other.

In this study, cadmium imidazolate frameworks were synthesized by a solvothermal method from acetate and 2-methylimidazole in an ethanol/methanol mixture. The Cd(Im)2 processed at 150 oC after 8 hours with the mixture of solvents has high crystallinity. appearance absorption band 407.73 cm-1 shows link formation Cd (II) N within HIm’s molecule. Cadmium only formats zeolite crystal, network fibe...

In the title complex, [Cd(C(2)F(3)O(2))(NO(3))(C(10)H(8)N(2))(2)], the Cd(II) ion is hepta-coordinated by two chelating 2,2'-bipyridyl ligands [Cd⋯N 2.370 (6)-2.416 (6) Å], one carboxyl-ate O atom [Cd⋯O 2.290 (6) Å] from the trifluoro-acetate ligand and two O atoms [Cd⋯O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoro-methyl fragment is rotationally disordered between two ...

Two series of Cd(II) coordination polymers (CPs), {[Cd(bimm)2(H2O)2][(3,4-tdc)2][H2O]2}n (1a), [Cd(3,4-tdc)(bimb)]n (2a), [Cd(3,4-tdc)(bimpy)(H2O)]n (3a) and [Cd(2,3-Htdc)2(bimm)2]n (1b), {[Cd(2,3-tdc)(bimb)](H2O)}n (2b), [Cd(2,3-tdc)(bimpy)(H2O)]n (3b) where H2tdc = thiophenedicarboxylic acid, bimm = 1,2-bis(imidazol-1'-yl)methane, bimb = 1,2-bis(imidazol-1'-yl)butane and bimpy = 3,5-bis(imida...

Fifty years ago, Dr Benjamin Castleman first described the unusual lymphoproliferative disorder that now bears his name. Over the subsequent decades, astute clinical and pathologic observations coupled with clever molecular biologic research have increased our understanding of the aetiology of Castleman disease (CD). This article proposes three broad CD variants based on both distinctive histop...

In the title complex, [Cd(CH(3)COO)(2)(C(4)H(8)N(2)S)(2)], the Cd(II) cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetra-hydro-pyrimidine-2(1H)-thione]. The Cd(II) coordination is augmented by one considerably longer Cd-O bond of 2.782 (3) Å to a carboxyl-ate O atom. The resulting coordination polyhedron around the Cd(II) cation...