Discovered over a century ago, Beckmann rearrangement is still today fully compliant with all the green chemistry principles and consistent key aspects of sustainable development. Herein, we report on mechanochemical procedure allowing design new amide frameworks via an eco-efficient “cut-and-paste” process C–C C–N bonds oxime backbone. We combined inexpensive readily available reagents, such a...

The main objective of the present work was to synthesis polyamide 6 through anionic polymerization of ε-caprolactam in an internal mixer. The reaction time and the rheological properties of samples during the polymerization were studied. The samples were characterized by Thermo Gravimetry Analysis (TGA), Differential Scanning Calorimeter (DSC) and FT-IR spectrometer. The melt flow behavior and ...