The structure-directing effect of amine has been observed in the ionothermal synthesis of aluminophosphate molecular sieves in 1-butyl-3-methylimidazolium bromide ionic liquid. The seven different amines we tested have an influence on the crystallization dynamics and the final product, leading to the formation of pure AFI and ATV structures.

benzo[b][1,4]oxazines have been synthesized in good to excellent yields in the presence of the ionic liquid 1-butyl-3methylimidazolium bromide [bmim]Br under relatively mild conditions without any added catalyst, the reaction workup is simple and the ionic liquid can be easily separated from the product and reused. Keywords—Isocyanide, Benzo[b][1,4]oxazines, Multi-component reactions, [bmim]Br,...

Activators regenerated by electron transfer (ARGET) atom radical polymerization (ATRP)-based aqueous miniemulsion where the takes place in stabilized monomer droplets is described. In this work, we compared styrene, n-butyl methacrylate (nBMA) and tert-butyl (tBMA) investigated influence of their hydrophobicity on dispersity, molecular weight particle stability based partition coefficients (log...

INTRODUCTION Extracorporeal Shock Wave Lithotripsy (ESWL) remains the preferred least invasive treatment for urinary tract stones. The main purpose of this study was to compare two treatment modalities for pain control during the ESWL procedure. MATERIAL AND METHODS From 2013 to 2014, 220 patients received ESWL for kidney stones. Before the procedure, the weight and height were measured to de...

In this work, we report about the mechanical relaxation characteristics of an intrinsically self-healable imidazole modified commercial rubber. This kind of self-healing rubber was prepared by melt mixing of 1-butyl imidazole with bromo-butyl rubber (bromine modified isoprene-isobutylene copolymer, BIIR). By this melt mixing process, the reactive allylic bromine of bromo-butyl rubber was conver...

The choice of analogue ion of the mobile phase additive is shown to significantly affect the analysis of quaternary ammonium compounds (QACs) in ion-pair reversed-phase high-performance liquid chromatography. A series of bromide-containing and dodecyl-sulfate-containing mobile phase additives are investigated using two QAC probe analytes. In all instances, the quaternary-ammonium-containing mob...

Electron transfer collisions between beams of neutral K atoms and neutral alkyl bromide ~R–Br! molecules (R5CH3 ,t-C4H9) are observed by detecting positive and negative ions in coincidence for energies *4 eV, the minimum energy for overcoming the Coulomb attraction between ions. The molecules are state selected by a hexapole electric field and oriented prior to the electron transfer. The steric...

A novel recognition method for selective determination of the hyoscine N-Butyl bromide (HBB), an antispasmodic agent for smooth muscles, was devised using extended gate field-effect transistor (EG-FET) as transducing unit. For this purpose a PVC membrane, containing hyoscine n-butyl-tetraphenyl borate ion-pair as recognition component, was coated on Ag/AgCl wire, which was connected to the exte...

An efficient enantioselective synthetic method for the synthesis of (2R)-5-phenyl-2-alkylproline tert-butyl esters was reported. The phase-transfer catalytic alkylation of tert-butyl-5-phenyl-3,4-dihydro-2H-pyrrole-2-carboxylate in the presence of chiral quaternary ammonium catalysts gave the corresponding alkylated products (up to 97% ee). The following diastereoselective reductions afforded c...