An iodide ion-selective PVC membrane sensor based on copper (Π)-bis-Nphenilsalicyldenaminatocomplex as a novel sensing material is successfully developed. Theelectrode showed a good selectivity for iodide ion with respect to common inorganic anions. Thesensor exhibited a good linear response with slope of _58.6 ± 0.4 mV per decade over theconcentration range of 5.0 × 10-6 to 1.0 × 10-1 mol L-1,...

A multi-walled carbon nanotube (MWCNT)-cetyltrimethylammonium bromide (CTAB) surfactant composite modified glassy carbon electrode (GCE) was developed as a novel system for the determination of 4-aminoantipyrine(AAP). The oxidation process was irreversible over the pH range studied and exhibited a diffusion controlled behavior. All experimental parameters were optimized. The combination of MWCN...

Nonresonant optical second harmonic generation (SHG) is used to monitor the adsorption of bisulfate, chloride, bromide, and iodide anions at polycrystalline platinum electrodes in aqueous solutions. Different polarization combinations of the fundamental and second harmonic beams are used to probe changes in the surface nonlinear susceptibility tensor elements caused by adsorption, reaction, and...

A simple physical model and theory have been proposed to investigate the electrocompression behavior of electrodeposited halide (chloride, bromide, and iodide) monolayer at the Au(111) electrode surface. By establishing the statistical thermodynamic formulas, the effective pair interaction energy, 2D spreading pressure, 2D isothermal compressibility, and electrode potential-coverage (θ-E) curve...

In this work, the results concerning to the mean activity coefficient measurements for NaCl in the (glycerol + water) system using the potentiometric method are reported. The potentiometric measurements were performed on the galvanic cells without liquid junction of the type: Ag|AgCl|NaCl (m), glycerol (wt%), H2O (1 - wt)%|Na-ISE, in various mixed solvent systems containing 0, 5, 10,...

We report the performance of a quinone-bromide redox flow battery and its dependence on electrolyte composition, flow rate, operating temperature, electrode and membrane materials and pre-treatment. The results of this study are used to develop a cell with a peak galvanic power density reaching 1.0 W/cm 2 .

1 The equilibrium coverage of metal electrodes in contact with an electrolyte has been addressed by periodic quantum-chemical calculations based density functional theory. The electrolyte has been treated in a grand-canonical approach using the concept of the computational hydrogen electrode. After briefly reviewing the theory and illustrating it using the co-adsorption of bromide and hydrogen ...