The design, synthesis, and investigation of new molecular oxygen probes for bioimaging, based on phosphorescent transition metal complexes are among the topical problems modern chemistry advanced bioimaging. Three iridium [Ir(N^C)2(N^N)]+ with cyclometallating 4-(pyridin-2-yl)-benzoic acid derivatives different di-imine chelate ligands have been synthesized characterized by mass spectrometry NM...