Transition metal oxides (TMOs) exhibit many emergent phenomena ranging from high-temperature superconductivity and giant magnetoresistance to magnetism and ferroelectricity. In addition, when TMOs are interfaced with each other, new functionalities can arise, which are absent in individual components. Here, we report results from first-principles calculations on the magnetism at the BiFeO3/YBa2...

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Autoimmune sera have been used in the diagnosis of autoimmune diseases as well as the analysis of nuclear substructures. In an attempt to study the biological characteristics of the nuclear matrix, we screened human sera using immunofluorescent staining and immunoblot. We detected antibodies against nuclear matrix (NM), a remnant nonchromatin protein compartment after the treatment of detergent...

Analysis of the 13C isotopic labeling patterns of nucleoside monophosphates (NMPs) extracted from Escherichia coli grown in a mixture of C-1 and C-2 glucose is presented. By comparing our results to previous observations on amino acids grown in similar media, we have been able to rationalize the labeling pattern based on the well-known biochemistry of nucleotide biosynthesis. Except for a few n...

Polarization-dependent two-dimensional infrared (2D IR) spectra of the purine and pyrimadine base vibrations of five nucleotide monophosphates (NMPs) were acquired in D(2)O at neutral pH in the frequency range 1500-1700 cm(-1). The distinctive cross-peaks between the ring deformations and carbonyl stretches of NMPs indicate that these vibrational modes are highly coupled, in contrast with the t...

Control over ferroelectric polarization variants in BiFeO3 films through the use of various vicinal SrTiO3 substrates is demonstrated. The ferroelectric polarization variants in these films are characterized by piezoelectric force microscopy and the corresponding structural variants are carefully analyzed and confirmed by X-ray diffraction. Implementation of this approach has given us the abili...

Epitaxial BiFeO3/SrRuO3 superlattices have been grown by pulsed laser deposition on a (001) oriented LaAlO3 substrate and probed X-ray diffraction Raman spectroscopy. To investigate the structural competition between rhombohedral BiFeO3 orthorhombic SrRuO3 total thickness of all SLs was kept constant bilayer (period) ? varied. The interlayer strain effects are therefore tuned from large (short ...

We report on electrically switchable polarization and ferroelectric domain scaling over a thickness range of 5–100 nm in BiFeO3 films deposited on [110] vicinal substrates. The BiFeO3 films of variable thickness were deposited with SrRuO3 bottom layer using the pulsed laser deposition technique. The domains are engineered into preferentially oriented patterns due to substrate vicinality along t...

In the past decade, self-assembled vertical nano-heterostructures have drawn considerable attention because a high interface-to-volume ratio can be used to tailor or create functionalities. We have systematically investigated the magnetic properties of oxide heterostructures consisting of the CoFe2O4 nanopillars embedded in the BiFeO3 matrix using macroscopic magnetization measurements and elem...

A promising approach for obtaining a large magnetoelectric response at room temperature in single-phase materials is to make use of phase-change phenomena structural instabilities multiferroic state. This the case perovskites showing morphotropic phase boundary (MPB) between ferroelectric polymorphs with differentiated magnetic orderings, like BiFeO3–PbTiO3. Indeed, distinctive effects were rec...