in this paper, cubic nickel oxide nanoparticles were successfully prepared by solid-state thermal decomposition of nickel(ii) macrocyclic schiff-base complex at 450°c for 3 h without employing toxic solvent or surfactant and complicated equipment. nickel(ii) macrocyclic schiff-base complex was synthesized by the reaction of 1,2-bis(2-formyl-3-methoxyphenyl)propane, nicl2•6h2o and 1,3-phenylened...

A family of artificial nucleosides has been developed by applying the Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition. Starting from 2-deoxy-β-D-glycosyl azide as a common precursor, three bidentate nucleosides have been synthesized. The 1,2,3-triazole involved in all three nucleobases is complemented by 1,2,4-triazole (TriTri), pyrazole (TriPyr), or pyridine (TriPy). Molecular structures of ...

Hydroxypyridone and pyridopurine homo- and hetero-base pairs have been investigated in the context of duplex GNA (glycol nucleic acid). Phosphoramidites for automated GNA solid phase synthesis were synthesized economically in a few steps starting from commercially available enantiopure glycidol. Similar to their behavior in DNA, the hydroxypyridone and pyridopurine homo-base pairs display a met...

The purpose of this study was to investigate the influence of the surface roughness of denture base resin and metal on wettability with water and saliva. Solid specimens were produced using heat-curing denture base resin and Co-Cr alloy. After polymerizing or casting these materials, specimens with four different types of surface roughness were produced by a progressive polishing process using ...

Catalytic hydrolysis technology of carbonyl sulfide (COS) at low temperature was reviewed, including the development of catalysts, reaction kinetics, and reaction mechanism of COS hydrolysis. It was indicated that the catalysts are mainly involved metal oxide and activated carbon. The active ingredients which can load on COS hydrolysis catalyst include alkali metal, alkaline earth metal, transi...

The high strength carbon steels such as API X65 is widely used to build the pipelines. In this study, the corrosion behavior welds region of the gas pipeline was studied. For this purpose, Shield Metal Arc Welding (SMAW) was used to evaluate the proposed method. The welding processes were performed with E6010, E6013, and ER70S-6 electrodes as filler metal and welding carried out in 3 passes by ...