In magnetic resonance imaging performed at fields of 1 T and above, the presence of a metal insert can distort the image because of susceptibility differences within the sample and modification of the radiofrequency fields by screening currents. Furthermore, it is not feasible to perform nuclear magnetic resonance (NMR) spectroscopy or acquire a magnetic resonance image if the sample is enclose...

The catalytic reduction of carbon dioxide is of great interest for its potential as a hydrogen storage method and to use carbon dioxide as C-1 feedstock. In an effort to replace expensive noble metal-based catalysts with efficient and cheap earth-abundant counterparts, we report the first example of Mn(i)-catalysed hydrogenation of CO2 to HCOOH. The hydride Mn(i) catalyst [Mn(PNPNH-iPr)(H)(CO)2...

We report about a 37 year old male patient with a pectus excavatum. The patient was in NYHA functional class III. After performed computed tomography the symptoms were thought to be related to the severity of chest deformation. A Ravitch-procedure had been accomplished in a district hospital in 2009. The crack of a metal bar led to a reevaluation 2010, in which surprisingly the presence of an a...

The impact of the intrinsic time-dependent fluctuations in the electrical resistance at the graphene-metal interface or the contact noise, on the performance of graphene field-effect transistors, can be as adverse as the contact resistance itself, but remains largely unexplored. Here we have investigated the contact noise in graphene field-effect transistors of varying device geometry and conta...

Use of the tritopic bridging ligand 1,3,5-benzenetristetrazolate (BTT3-) enables formation of [Mn(DMF)6]3[(Mn4Cl)3(BTT)8(H2O)12]2.42DMF.11H2O.20CH3OH, featuring a porous metal-organic framework with a previously unknown cubic topology. Crystals of the compound remain intact upon desolvation and show a total H2 uptake of 6.9 wt % at 77 K and 90 bar, which at 60 g H2/L provides a storage density ...

Understanding the mechanism of gas-sorbent interactions is of fundamental importance for the design of improved gas storage materials. Here we report the binding domains of carbon dioxide and acetylene in a tetra-amide functionalized metal-organic framework, MFM-188, at crystallographic resolution. Although exhibiting moderate porosity, desolvated MFM-188a exhibits exceptionally high carbon dio...

The metal-free catalytic hydrogenolysis of silyl triflates and halides (I, Br) to hydrosilanes is unlocked by using arylborane Lewis acids as catalysts. In the presence a nitrogen base, catalyst acts Frustrated Pair (FLP) able split H2 generate boron hydride intermediate capable reducing (pseudo)halosilanes. This organocatalytic system competitive with metal-based catalysts enables formation va...

We present analysis of nearly 1,000 near-infrared, integrated light spectra from APOGEE in the inner $\sim$7 kpc M31. utilize full spectrum fitting with A-LIST simple stellar population spectral templates that represent a stars same age, [M/H], and [$\alpha$/M]. With this, we determine mean kinematics, metallicities, $\alpha$ abundances, ages populations M31's bar, bulge, disk ($\sim$4-7 kpc). ...

‎Let $tau$ be a subgroup functor and $H$ a $p$-subgroup of a finite group $G$‎. ‎Let $bar{G}=G/H_{G}$ and $bar{H}=H/H_{G}$‎. ‎We say that $H$ is $Phi$-$tau$-quasinormal in $G$ if for some $S$-quasinormal subgroup $bar{T}$ of $bar{G}$ and some $tau$-subgroup $bar{S}$ of $bar{G}$ contained in $bar{H}$‎, ‎$bar{H}bar{T}$ is $S$-quasinormal in $bar{G}$ and $bar{H}capbar{T}leq bar{S}Phi(bar{H})$‎. ‎I...

In this study, the applicability of nanofiltration (NF) membranes as a pretreatment prior to reverse osmosis (RO) in seawater desalination was investigated. The membranes used wereNF270 and NF90 as the NF membranes, while the brackish water (BW) RO membrane BW30 was used as the RO membrane. In desalination tests, permeates of the NF membraneswere collected and used as the feed to th...