The basics of quantum mechanics and statistical thermodynamics were used to predict the potential energy and intermolecular forces of asphaltene molecules. The parameters associated with the chemical structure were also estimated for a specific asphaltene molecule to predict the Mie potential function. Based on the structural results, a new form of the Virial EOS with Peneloux correction wa...

Onset of asphaltene precipitation is the key parameter in dealing with asphaltene problems because it is the starting point of the asphaltene separation from the solution. In this study, a new technique is provided based on the experimental observations for the determination of the onset of asphaltene precipitation using accurate density measurements of the crude oils upon titration with precip...

The use of nanoparticles, including metal oxide surfaces, as asphaltene adsorbents is a potential method of removing and/or upgrading asphaltenes. The adsorption of two asphaltene types, extracted from two types of Iranian crude oil, onto nanoparticles (TiO2, SiO2, and Al2O3) are assessed and the thermal behavior of the adsorbed asphaltenes is examined under an oxidizing atmosphere through ther...

The molecular-mass distribution of the asphaltene fraction of petroleum is rapidly becoming more constrained, but themolecular architecture remains poorly understood. Two types of molecular structures have been proposed to be representative of asphaltenes: the “island” model and the “archipelago” model. Here, nine compounds were synthesized on the basis of pyrene, representing both types of mod...

The asphaltene fraction of crude oils is one of the main factors defining wettability conditions and ultimate oil recovery. At reservoir scale asphaltenes may cause reservoir compartmentalization and at pore scale govern wettability phenomena. To reproduce reservoir conditions, aging in oil is a common step in laboratory core analysis. Oils relevant to the origin of the plugs are the apparent c...

Energy & Fuels is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Article Sensitivity of Asphaltene Properties to Separation Techniques H. Alboudwarej, J. Beck, W. Y. Svrcek, H. W. Yarranton, and K. Akbarzadeh Energy Fuels, 2002, 16 (2), 462-469• DOI: 10.1021/ef010213p • Publication Date (Web): 06 February 2002 Downloaded from http://pubs.acs.org on ...

Here, we investigate the surface shear rheology of class II HFBII hydrophobin layers at the oil/water interface. Experiments in two different dynamic regimes, at a fixed rate of strain and oscillations, have been carried out with a rotational rheometer. The rheological data obtained in both regimes comply with the same viscoelastic thixotropic model, which is used to determine the surface shear...

Experiments are described which demonstrate that asphaltenes precipitated from a refinery tar using an excess of n-heptane spontaneously partition into a contacting water phase in the presence of an ethoxylated nonionic surfactant by effecting a temperature change. The process appears to be related to the temperature-dependent phase behaviour of the particular surfactant. Hot (ca. 80-90°C) aque...