The gravimetric analysis of antimony(III) with oxine (8-quinolinol, Hox) was studied. The amount of antimony left in filtrate and washing solutions was corrected with the results of atomic absorption spectrometry. The weighing form, which had not been conclusive before the present study, was determined to be SbO(ox)(Hox)2. The result (purity of antimony(II) oxide: 99.84 +/- 0.05% (m/m)) of the ...

Over a century ago, in 1835, Leopold Gmelin' prepared the substance tripotassium hydromelonate by heating potassium ferrocyanide with sulfur; he also made other salts of hydromelonic acid, and carried out analyses, which, however, were not sufficiently accurate to lead to correct formulas. He recognized the similarity of the substances to the group of nitrogen compounds discovered and named by ...

A sensitive atomic spectrometric method for the redox speciation analysis of antimony in soils is described. The method is based on the selective generation of stibine from Sb(III) in a continuous flow system using atomic fluorescence spectrometry for detection. Sb(V) is masked by citric or oxalic acid in HCl medium. The procedure was optimized with synthetic solutions of Sb(III) and Sb(V). The...

Elemental antimony occurs in the solid bulk in a metallic as well as an amorphous modification.[1] Over a wide temperature range the gas phase of elemental antimony comprises almost exclusively of tetrameric molecules;[2] however, a solid-state modification of antimony consisting of Sb4 molecules, comparable to white phosphorus and yellow arsenic, is not known to date. This is explained by the ...