Alkyl-cyclohexanes can be considered as suitable model compounds to understand the thermochemistry of aromatic and their hydrogenated counterparts discussed Liquid Organic Hydrogen Carrier systems. Thermochemical measurements on these hydrogen-rich are thwarted by complications due 99.9 % purity limitation sample size specific methods. However, data vaporisation formation enthalpies necessary o...

silica chloride converted benzyl or tert-butyl esters to the corresponding acid chlorides and alkyl chlorides. it also converted benzyl or tert-butyl phenyl ethers to the corresponding allcyl chlorides and phenol

the synthesis of a novel class of 2-oxoindolin-3-ylidene-(1-arylhydrazinyl)-2-aryl(alkyl)ethylidene derivativesvia a copper-catalyzed tandem reaction of isatin, arylhydrazines, sulfonyl azides and terminal alkynes is described.

Alkyl (S)-lactate and alkyl (S,S)-lactyllactate were rapidly and conveniently synthesized from L-lactide using Group 1 and 2 metal complexes as catalyst in alcohol.

The synthesis of new pinene-derived chiral cyclopropylamines and their use in the synthesis of the first asymmetric Alkyl-BIAN ligands (Alkyl-BIAN = bis-(alkylimino)acenaphthenequinone) are reported.

Two bolaamphiphilic compounds with identical acetylcholine (ACh) head groups, but with different lengths of an alkyl chain pendant adjacent to the head group, as well as differences between their hydrophobic skeleton, were investigated for their ability to self-assemble into vesicles that release their encapsulated content upon hydrolysis of their head groups by acetylcholinesterase (AChE). One...

A series of C4-C 12 alkyl acrylates and methacrylates was polymerized with starch by irradiating starch-monomer mixtures with 60CO. Homopolymers were extracted with cyclohexane. The amounts of insoluble versus soluble synthetic polymer in polymerizations run with alkyl acrylates varied less with the chain length of the alkyl substituent than in the polymerizations run with alkyl methacrylates: ...

In previous work we found that sterols such as cholesterol were essential for physiological plasma clearance of lipid emulsions mimicking the structure of mammalian triglyceride-rich lipoproteins. In the present study we compared the clearances of emulsions prepared with sterols of varying alkyl chain length (straight chains, n-C3 to n-C7, or branched chains, i-C5 to i-C10) at the C-17 position...

Poly(L-lactide) (PLLA) oligo-esters with α-hydroxyl-ω-alkyl (alkyl = −CH2−[CH2−CH2]n−CH3, where n = 1, 2, 4, 5, 6, 7, 8, 9, and 10) end groups were synthesized by ring-opening polymerization of L-lactide (L-LA) catalyzed by tin(II) 2ethylhexanoate Sn(Oct)2 in the presence of aliphatic alcohols as initiators (HO−CH2−[CH2−CH2]m−CH3, where m = 1, 2, 4, 5, 6, 7, 8, 9, and 10). High yields (∼ 62 to ...