We investigate the properties of alkali-alkaline earth diatomic molecules in the lowest Σ(+) states of the doublet and quartet multiplicity by ab initio calculations. In all sixteen cases studied, the permanent electric dipole moment points in opposite directions for the two spin states. This peculiarity can be explained by molecular orbital theory. We further discuss dissociation energies and ...

Nucleobase tautomers and their metal complexes have attracted considerable attention due to their fascinating architectures along with wide applications. In this paper, 4,6-dihydroxypyrimidine (H(2)DHP), an analogue of uracil and thymine, was employed to react with the vital elements of alkaline earth metals in an aqueous solution and lead to the formation of four novel complexes, [Mg(HDHP)(2) ...

Formation of carbonate minerals by CO2 sequestration is a potential means to reduce atmospheric CO2 emissions. Vast amount of alkaline and alkali earth metals exist in silicate minerals that may be carbonated. Laboratory experiments carried out to study the dissolution rate in Pahang Sandstone, Malaysia, by CO2 injection at different flow rate in surficial condition. X-ray Powder Diffraction (X...

The extraction-separation of alkali, alkaline earth, and rare earth metal ions could be improved by using macrocyclic ligands as ion size selective masking reagents. By adding a macrocyclic ligand to the aqueous phase of a conventional chelate extraction system, the extraction of metal ions with larger ionic radii was shifted to a higher pH region. Consequently, the separation among the metal i...

THE MINING REPORT Luisa Moreno, managing partner and analyst with Toronto-based Tahuti Global, says there are many things investors must pay attention to when it comes to critical metals projects, but nothing should trump metallurgy. That's because no two deposits are precisely the same, and having a clear understanding of how to economically recover those metals and get them into end-users' ha...

A spectre-photometric method is described for the determination of magnesium* calcium, strontium and barium coexisting in binary mixtures. The method employs totramethyimurexide as an auxiliary ligand, and has been developed for pure two-component systems, such as are involved in investigations of cation-exchange equilibria on anionic polymers. The analysis is performed with calibration curves ...

The challenge in preparation of ionic liquids containing a strong alkaline anion is to identify a suitable cation which can tolerate the harsh conditions induced by the anion. In this study, a commercial quaternary ammonium compound (quat) benzalkonium [ADBA] (alkyldimethylbenzylammonium) was used as a cation in the synthesis of different alkaline ionic liquids. In fact, the precursor, benzalko...

The capacity of bacteria to survive and grow at alkaline pH values is of widespread importance in the epidemiology of pathogenic bacteria, in remediation and industrial settings, as well as in marine, plant-associated and extremely alkaline ecological niches. Alkali-tolerance and alkaliphily, in turn, strongly depend upon mechanisms for alkaline pH homeostasis, as shown in pH shift experiments ...

All-inorganic metal halide perovskite nanocrystals (NCs) having the general formula ABX3, where A is a monovalent cation, for example, Cs+, B divalent typically Pb2+, and X Cl–, Br–, I–, or their binary mixture, show potential in optoelectronic devices. In this work, we explore effect of B-site doping on properties CsPbX3 NCs (X = Br, Cl). First, Pb2+ ions pristine CsPbBr3 NC are partially subs...