We report density functional electronic structure calculations to monitor the change in the surface characteristics of the Si (100)-2x1 surface after fluorination followed by interaction with water. Embedded finite silicon clusters are used to model an extended Si (100)-2x1 surface. Two high symmetry pathways and subsequent adsorption sites were examined: (i) adsorption of an fluorine atom dire...

This study demonstrates the potential of a newBiOCl0.875Br0.125 photocatalyst to degrade pharmaceuticals in water (i.e., carbamazepine (CBZ), ibuprofen (IBF), bezafibrate (BZF), and propranolol (PPL)), under simulated solar irradiation. Different parameters were examined through their influence on CBZ degradation. Increasing the catalyst concentration up to 500 mg/L increased CBZ degradation ra...

Polymer adsorption is a fundamental problem in statistical mechanics that has direct relevance to diverse disciplines ranging from biological lubrication to stability of colloidal suspensions. We combine experiments with computer simulations to investigate depletion induced adsorption of semi-flexible polymers onto a hard-wall. Three dimensional filament configurations of partially adsorbed F-a...

pollution of water resources by various pollutants is nowadays a global environmental issue. among the different type of water pollutants, dye represents a major polluting group. in this study, azolla filiculides roots have been used for adsorption of malachite green (mg), a cationic dyed from aqueous solution. in this study, effects of operating parameters such as initial concentration of dye ...

removal of cesium from synthetic aqueous solution through adsorption on vermiculite, under batch equilibrium experimental condition at six initial values of ph (3, 4, 6, 9, 11 and 12) and five temperatures (25, 50, 75, 85 and 95 °c) has been investigated. it is necessary to propose a suitable model for a better understanding of the mechanism of cesium adsorption on vermiculite. for this propose...

this paper deals with application of polyaniline coated on wood sawdust for removal ofmethylene blue (mb) dye from aqueous solutions. polyaniline coated onto sawdust (termedas pan/sd) was prepared via direct chemical polymerization onto sawdust which waspreviously soaked in the monomer (aniline) solution in acidic (hc1) media. adsorptionexperiments were carried out using batch system. the effec...

introduction: boron (b) is an essential plant micronutrient whose soil availability is influenced by many soil factors.understanding the processes controling activity of boron (b) in the soil solution is important for soil fertility management. the reaction of adsorption and desorption of boron in soil determines the amount of boron that is available to plants. adsorption–desorption processes p...

Adsorption of hexavalent chromium [Cr(VI)] onto a loamy sand soil was studied using batch and steady flow tests with contaminant solutions at pH 2, 5 and 7. In all the cases the adsorption of Cr(VI) decreased with increasing pH. The hexavalent chromium speciation and its presence as different oxyanions, according to the solution pH, were the main variables affecting the adsorption process. The ...

This study presented an original on the F- removal by Fe and Zr doped Gismondine-dominated Zeolite. Various modified zeolites are prepared systematically adjusting synthesis variables, namely pH, mass ratio of zeolite to modify agent (mZeolite:m(Fe+Zr)), (Fe:Zr) investigate their effects adsorption. The performance Fe-Zr-Zeolite was examined through both statistic adsorption dynamic Results ind...