نتایج جستجو برای: activation entropy
تعداد نتایج: 491900 فیلتر نتایج به سال:
The dissociation mechanism of duplex DNA has been investigated in detail by collision-induced dissociation experiments at different collision regimes. MS/MS experiments were performed either in a quadrupole collision cell (hybrid quadrupole-TOF instrument) or in a quadrupole ion trap with different activation times and energies. In addition to the noncovalent dissociation of the duplex into the...
Benzenoid hydrocarbons have regular structures, attracting the opportunity to test structural descriptors of their series. In present study, we compared information entropy, Wiener indices, topological efficiencies, roundness, and symmetries oligoacenes, phenacenes, helicenes. We found discussed mismatches between symmetry benzenoids. Among studied series, helicenes demonstrate parity effect wh...
wear is a complicated phenomenon caused by the relative movement of two contacting surfaces compressed together by a normal force. prediction of the wear, in most cases, requires various experiments and microstructural characterization of the contacting surfaces. mathematical models based on physical concepts could provide considerable help in understanding the physical behavior and hence the p...
entropy as a measure of uncertainty was used to represent the results of the wavelet technique in electrochemical noise analysis. the experimental signals were obtained by recording the electrochemical potential and current noise of 7075 aluminum alloy in 3.5% nacl solution. the electrochemical potential and current noise were decomposed into 16 levels using daubechies wavelets. wavelet output ...
In this paper an approximation for entropy rate of an ergodic Markov chain via sample path simulation is calculated. Although there is an explicit form of the entropy rate here, the exact computational method is laborious to apply. It is demonstrated that the estimated entropy rate of Markov chain via sample path not only converges to the correct entropy rate but also does it exponential...
The combined effects of magnetic field, Navier slip and convective heating on the entropy generation in a flow of a viscous incompressible electrically conducting fluid between two infinite horizontal parallel plates under a constant pressure gradient have been examined. Both the lower and upper plates of the channel are subjected to asymmetric convective heat exchange with the ambient fluid. T...
We study the entropy rate of a hidden Markov process, defined by observing the output of a symmetric channel whose input is a first order Markov process. Although this definition is very simple, obtaining the exact amount of entropy rate in calculation is an open problem. We introduce some probability matrices based on Markov chain's and channel's parameters. Then, we try to obtain an estimate ...
Complexity (or its opposite, regularity) of heart period variability has been related to age and disease but never linked to a progressive shift of the sympathovagal balance. We compare several well established estimates of complexity of heart period variability based on entropy rates [i.e., approximate entropy (ApEn), sample entropy (SampEn), and correct conditional entropy (CCE)] during an ex...
In this paper we study the relative entropy rate between a homogeneous Markov chain and a hidden Markov chain defined by observing the output of a discrete stochastic channel whose input is the finite state space homogeneous stationary Markov chain. For this purpose, we obtain the relative entropy between two finite subsequences of above mentioned chains with the help of the definition of...
in this paper, the ambiguity of nite state irreducible markov chain trajectories is reminded and is obtained for two state markov chain. i give an applicable example of this concept in president election
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