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Locusta migratoria feeds on various Poaceae plants but barley. Barley genes related to feeding deterrence may be useful for developing novel resistant crops. We investigated the effects of barley cultivar Betzes, wheat cultivar Chinese Spring (CS), and six barley chromosome disomic addition lines of wheat (2H-7H) on locomotor activity, feeding behavior, survival and development of L. migratoria...
Rational design, synthesis, and biological activity of benzoxazinones as novel factor Xa inhibitors.
Inappropriate thrombus formation within blood vessels is the leading cause of mortality in the industrialized world. Factor Xa (FXa) is a trypsin-like serine protease that plays a key role in the blood coagulation cascade and represents an attractive target for anticoagulant drug development. From a high-throughput in vitro mass screen of our chemical library, we identified 4-[5-[(2R,6S)-2, 6-d...
A superhydrophobic surface is coated on the surface of a cloth by MTCS (methyltrichlorosilane) nanoparticles and then, it is modified by SiO2–m–FTCS (1H,1H,2H,2H-Perfluorododecyltrichlorosilane) nanoparticles. This surface is characterized by SEM(scanning electron microscopy), and FT-IR (Fourier transform-infrared microscopy) and also its contact angle is investigated in various conditions and ...
برای هر عدد صحیح مثبت m و به ازای w=(q^(m+1)-1)/(q-1) می توان یک (vw,kq^m,?q^m)- طرح متقارن ساخت. اگر h یک ماتریس آدامار منظم با جمع سطری 2h، m یک عدد صحیح مثبت و q=?(2h-1)?^2 توانی از یک عدد اول باشد در این صورت با استفاده از bgw((q^(m+1)-1)/(q-1),q^m,q^m-q^(m-1)) می توان طرح متقارن با پارامترهای ((4h^2 (q^(m+1)-1))/(q-1),(2h^2-h) q^m,(h^2-h) q^m) ساخت هرگاه h در شرایط خاصی صدق کند. چنین شرایط...
Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans
Asymmetric allylic alkylation is a powerful reaction that allows the enantioselective formation of C-C bonds. Here we describe the asymmetric alkylation of alkylzirconium species to racemic 3,6-dihydro-2H-pyrans. Two systems were examined: 3-chloro-3,6-dihydro-2H-pyran using linear optimization (45-93% ee, up to 33% yield, 5 examples) and 3,6-dihydro-2H-pyran-3-yl diethyl phosphate with the ass...
In this study a series ofnew1-(2-aryl-5-phenethyl-1,3,4-oxadiazol-3(2H)-yl)ethanones 2a-e was synthesized by the cyclization of imines 1a-e using acetic anhydride. The products were evaluated for anti-bacterial and anti-fungal activity. Among the newly synthesized compounds, 1-(2-(4-(dimethylamino)phenyl)-5-phenethyl-1,3,4-oxadiazol-3(2H)-yl)ethanone (2a)and1-(2-(4-chlorophenyl)-5-phenethyl-1,3...
Three coumarin-derived fluorescent probes, 3-acetyl-7-[(6-bromohexyl)oxy]-2H-chromen-2-one (FM1), 7-[(6-bromohexyl)oxy]-4-methyl-2H-chromen-2-one (FM2) and ethyl 2-{7-[(6-bromohexyl)oxy]-2-oxo-2H-chromen-4-yl}acetate (FM3), are described, with their photophysical constants. The compounds were tested in preliminary studies employing epifluorescence microscopy demonstrating that they allow the im...
Exhaustive hydro-distillation of the bark, heartwood and fruits of Cryptocarya massoy (Lauraceae) afforded pale yellow-coloured oils in 0.7, 1.2 and 1.0 % yields, respectively. Detailed chemical evaluation of these distillates using GC/MS revealed the major components in the bark and the heartwood oils to be the C-10 (5,6-dihydro-6-pentyl-2H-pyran-2-one) and C-12 (5,6-dihydro-6-heptyl-2H-pyran-...
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