The binary adsolubilization behaviors of 2-naphthol +biphenyl and 2-naphthol +1, 3-dichlorobenzene in a cationic fluorocarbon surfactant adsorbed layer formed on TiO2 have been investigated as a function of pH. In the binary adsolubilization of 2-naphthol+biphenyl, the adsolubilized amount of 2-naphthol increases gradually until pH 7 and then sharply with a further increase of pH, whereas the a...

a solid chelating material, 1-(2-pyridy1azo)-2-naphthol (pan) supported on naphthalene provides a rapid and highly selective means of preconcentration of uranium from aqueous solution. uranium is quantitatively retained on this adsorbent in the ph range 9.8-10.7 with a flow rate of 1 ml min . the metal complex was desorbed with 10 ml of 2 m hydrochloric acid and uranium is determined by differe...

In liquid-liquid extraction performed by monosegmented flow analysis (MSFA), the aqueous sample is introduced between two air bubbles and flows, under restricted dispersion, through a glass extraction tube where the analyte is retained, usually at pH higher than 8. The retained analyte is removed to a small volume of an organic phase containing a ligand which is introduced after the second air ...

Of two sensitive complexometric reagents for the colorimetry of serum zinc that we investigated, one, 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (Br-PADAP), was found to be a potentially useful compound for trace-metal determinations. It has a high molar absorptivity (120 000 L mol-1 cm-1) but is not convenient to use because it is not very soluble in water. The other reagent, a related pyri...

A solid chelating material, 1-(2-pyridy1azo)-2-naphthol (PAN) supported on naphthalene provides a rapid and highly selective means of preconcentration of uranium from aqueous solution. Uranium is quantitatively retained on this adsorbent in the pH range 9.8-10.7 with a flow rate of 1 ml min . The metal complex was desorbed with 10 ml of 2 M hydrochloric acid and uranium is determined by d...