The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions.

Hollow silica tubes with mesoporous wall structure were synthesized through the sol-gel reactions of tetraethoxysilane and n-octadecyltrimethoxysilane (TEOS/C18-TMS) on the surface of ammonium dl-tartrate crystals. Novel hollow carbon tubes with mesoporous walls and rectangular-shaped channels were fabricated using the silica tubes as templates.

Submit Manuscript | http://medcraveonline.com Abbreviations: ILs: Ionic Liquids; CMNPs: Citrate-Coated Magnetite Nanoparticles; TEOS: Tetraethoxyorthosilicate; CPTMS: 3-Cloropropyltrimethoxysilane; IM: Imidazole; XRD: X-Ray Diffraction; FT-IR: Fourier-Transform Infrared Spectroscopy; TGA: Thermal Gravimetric Analysis; VSM: Vibrating-Sample Magnetometer; SEM: Scanning Electron Microscope; TLC: T...

Arvosteltu teos: Karppinen-Kummunmäki, Henna 2022. Tyttöjen vuosisadat: Lasten ja nuorten historiaa keskiajalta 1800-luvulle. Helsinki: Avain. 250 s.

The use of organic–inorganic hybrid compounds containing tetraethoxysilane (TEOS) and hydroxyl-terminated polydimethylsiloxane (PDMS-OH) is one of the most promising approaches for using alkoxysilane-based formulations to improve the effectiveness of the consolidation of traditional silicate artifacts, such as ancient stone. Based on analysis of existing damaged potteries influenced by the crys...

Introduction A major challenge faced by ceramic chemists today is the production of fully polymerized silica by low temperature (< 50°C) solution routes. Current methods involve high temperature, extreme pH, or both. Biological systems, however, have the ability to produce silica under much more benign conditions. These include near neutral pH and temperatures at or below room temperature. Our ...