In this work, we demonstrate a facile successive ionic layer adsorption and reaction process accompanied by hydrothermal method to synthesize CdS nanoparticle-modified α-Fe2O3/TiO2 nanorod array for efficient photoelectrochemical (PEC) water oxidation. By integrating CdS/α-Fe2O3/TiO2 ternary system, light absorption ability of the photoanode can be effectively improved with an obviously broaden...

T dioxide (TiO2), due to its excellent solid-state physical-chemical properties, has demonstrated a wide range of applications in hydrogen production, lithium-ion batteries, fuel cells, gas sensors, detoxification, photovoltaics, photocatalysts, and supercapacitors. The one-dimensional (1D) morphology, such as a TiO2 nanowire (NW), is considered as a superior candidate for achieving higher perf...

A variety of combinations of CdS, TiO2, and Pt in preparing the hybrid catalysts were studied for hydrogen production under visible light (l > 420 nm) irradiation. The preparation method sensitively influenced the activity of the ternary hybrid catalysts. The formation of the potential gradient at the interface between CdS and TiO2 is necessary in achieving the efficient charge separation and t...

0014-3057/$ see front matter 2008 Elsevier Ltd doi:10.1016/j.eurpolymj.2008.06.002 * Corresponding author. Tel.: +86 451 82518 82518644. E-mail address: [email protected] (X. Lu). A new method of surface modification of TiO2 nanoparticles by surface-grafting L-lactic acid oligomer was developed. The surface-grafting reaction was evaluated by Fourier transformation infrared (FTIR) and thermal ...

Key biological functions involved in cell survival have been studied to understand the difference between the impact of exposure to TiO2 nanoparticles (TiO2-NPs) and their bulk counterparts (bulk-TiO2). By selecting a unicellular eukaryotic model organism and applying proteomic analysis an overview of the possible impact of exposure could be obtained. In this study, we investigated the early re...

Two series of Fe2O3/TiO2 samples were prepared via impregnation and photodeposition methods. The effect of preparation method on the properties and performance of Fe2O3/TiO2 for photocatalytic degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) under UV light irradiation was examined. The Fe2O3/TiO2 nanocomposites prepared by impregnation showed lower activity than the unmodified TiO2, mainly...

We develop a composite photoanode by sensitizing TiO2 nanorod arrays with PbS quantum dots (QDs) and CdS QDs. Benefitted from additional introduced PbS QDs and CdS QDs onto TiO2, the absorption of the composite photoanodes are broaden from UV to visible region. The experimental results showed that the PbS sandwiched between TiO2 and CdS cannot only broad the absorption properties but also impro...

TiO2 nanoparticle (NP)/ITO nanowire (NW) nanocomposites for use as photoelectrode materials were fabricated to improve the charge collection efficiency in solid state dye sensitized solar cells (ss-DSSCs). The average current density for ss-DSSCs containing TiO2 NP/ITO NW arrays was 7.2 mA cm(-2) that was 98% higher than that for the conventional TiO2 NP ss-DSSCs. The intensity modulated photoc...

The efficiency of dye-sensitized solar cells (DSCs) depends critically on the electronic structure of the interfaces in the active region. We employ recently developed dispersion-inclusive density functional theory (DFT) and GW methods to study the electronic structure of TiO2 clusters sensitized with catechol molecules. We show that the energy level alignment at the dye-TiO2 interface is the r...

Development of nanostructured photocatalysts for harnessing solar energy in energy-efficient and environmentally benign way remains an important area of research. Pure and WO3-surface modified thin films of TiO2 were prepared by magnetron sputtering on indium tin oxide glass, and photoelectrochemical and photocatalytic activities of these films were studied. TiO2 particles were <50 nm, while de...