Two methods for cross-selectivity enhancement of porous poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP)/carbon black (CB) composite-based resistive sensors are provided. The sensors are tested with acetone and ethanol in the presence of humid air. Cross-selectivity is enhanced using two different methods to modify the basic response of the PVDF-HFP/CB sensing platform. In method I, the...

Carbon coated boron nitride nanosheets (BNNSs@C) hybrids with different carbon contents were synthesized by a chemical vapor deposition (CVD) method. The content of carbon in as-obtained BNNSs@C hybrids could be precisely adjusted from 2.50% to 22.62% by controlling the carbon deposition time during the CVD procedure. Afterward, the BNNSs@C hybrids were subsequently incorporated into the polyvi...

Poly(vinylidene fluoride-co-tetrafluoroethylene) (PVDF-TFE) is confined between alternating layers of poly(ethylene terephthalate) (PET) utilizing a unique multilayer processing technology, in which PVDF-TFE and PET are melt-processed in a continuous fashion. Postprocessing techniques including biaxial orientation and melt recrystallization were used to tune the crystal orientation of the PVDF-...

This study is focused on forming a fibrous-zinc oxide/ polyvinylidine fluoride (ZnO/PVDF) nanocomposite and characterizing its dielectric behavior. The nanocomposite is prepared in two steps. First, a network of nanoscale diameter ZnO fibers is produced by sintering electrospun PVA/Zinc Acetate fibers. Second, the ZnO fibrous nonwoven mat is sandwiched between two PVDF thermoplastic polymer fil...

– The electronic structure and band symmetries of the ferroelectric phase of poly (vinylidene fluoride) (PVDF) are studied by using the first-principles density-functional method. Our calculated results agree well with the angle-resolved photoemission experiments. We find that the PVDF crystal has an energy gap of about 6 eV at the Γ-point. Large dispersion of the valence band is found only alo...

Hybrid materials based on ionic liquids (ILs) and polymers are increasingly being used for the development of smart multifunctional materials, allowing to tune polymer properties or introduce new ones. Nonetheless, structural organization ILs within matrix is not properly understood. This work reports different incorporated into polyvinylidene fluoride (PVDF) films. The effect IL type ([Pmim][T...

Additively manufactured flexible and high-performance piezoelectric devices are highly desirable for sensing energy harvesting of 3D conformal structures. Herein, the study reports a significantly enhanced piezoelectricity in polyvinylidene fluoride (PVDF) achieved through situ dipole alignment PVDF within PVDF-2D molybdenum disulfide (2D MoS2) composite by printing. The shear stress-induced po...

Abstract In this work, a synthesis to improve surface wetting resistance composites via infusion of graphene (G) structure into the polyvinylidene fluoride (PVDF) matrices is introduced. Graphene incorporated PVDF matrix with percentage 1.0 wt.% up 2.5 using simple solvent blending and dry-casting methods. The morphological structural properties infused are investigated variety characterization...

We used first principles methods to study static and dynamical mechanical properties of the ferroelectric polymer poly(vinylidene fluoride) (PVDF) and its copolymer with trifluoro ethylene (TrFE). We use density functional theory [within the generalized gradient approximation (DFT-GGA)] to calculate structure and energetics for various crystalline phases for PVDF and P(VDF-TrFE). We find that t...

The outermost nanometres of a poly(vinylidene difluoride) (PVdF) based coil coating have been investigated using X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). A reference PVdF based coating formulation and three variations of this formulation were characterised by XPS. The addition of flow agent and/or acrylic co-polymers induced significa...