Two XRF specimen preparation methods were investigated for quantifying gallium in plutonium metal. Gallium in plutonium was chosen here as an example for demonstrating the efficacy of wavelength dispersive XRF for quantifying radioactive materials. The steps necessary to handle such materials safely will also be discussed. Quantification of plutonium samples by a wellestablished aqueous specime...

New plastic certified reference materials (CRMs) with Pb, Cd and Cr for XRF analysis have been developed in cooperation with the Japan Society for Analytical Chemistry. These CRMs (named as JSAC 0611 – 0615) were prepared by casting polyester including a toluene solution of organometallic compounds as a standard. The disk was removed from the glass plate after 12 h of hardening at room temperat...

Analysis of rodent brains with X-ray fluorescence (XRF) microscopy combined with immunohistochemistry allowed us to demonstrate that local Cu concentrations are thousands of times higher in the glia of the subventricular zone (SVZ) than in other cells. Using XRF microscopy with subcellular resolution and intracellular X-ray absorption spectroscopy we determined the copper (I) oxidation state an...

Given the paucity of empirical constraints, the nature of the newly-recognized phenomena called X-Ray Flashes (XRFs) has been an open question. However, with the recent detections of radio and X-ray afterglow it is finally possible to study the large-and small-scale environments of XRFs. We present Chandra, Hubble Space Telescope (HST), and Keck observations of the fields of XRFs 011030 and 020...

Setting up a system for first order results is straightforward. One can easily identify the major constituents in simple samples and obtain approximate concentrations. This is sufficient for some applications. However, second order effects are quite important for many applications. To obtain high accuracy, identify constituents with low concentrations, or operate on a wide variety of samples, s...

The particulate matter (PM) concentration and composition, the PM10, PM2.5, PM1 fractions, were studied in the urban area of Genoa, a coastal town in the northwest of Italy. Two instruments, the continuous monitor TEOM and the sequential sampler PARTISOL, were operated almost continuously on the same site from July 2001 to September 2004. Samples collected by PARTISOL were weighted to obtain PM...

Due to their non-destructive character, X-ray analytical methods are widespread in the field of archaeometry. In the present study, the use of synchrotron radiation induced X-ray fluorescence analysis (SR-XRF) is illustrated on three examples: a silver point drawing of Jan van Eyck, the Hiddensee Gold Treasure, and the Sky Disc of Nebra. The possibility to analyse large objects in normal atmosp...

Handheld X-ray fluorescence spectrometry (HH-XRF) has been established as the gold standard method for in-situ elemental determination in metals and alloys in the last 10 years. More than 5,000 analyzers are sold yearly worldwide for scrap metals sorting and positive material identification (PMI). PMI is a quality assurance tool consisting of the identification of alloy grades in various indust...

This paper presents the framework and results of analysis of the building materials used in traditional Chinese copper halls. The analysis of the Kunming copper hall (KCH) is presented as a typical example. First, the historical building structure of the KCH is investigated. Results of X-ray fluorescence (XRF) spectrometry are presented and analyzed according to the units of each building compo...

The usage of wastes of baggase would be admirable from environmental and solid waste management point of view. Thus, herein, this data set present a facile method for providing an adsorbent from mixture of bagasse-bentonite. The prepared adsorbent was applied to remove Cd2+ from aqueous solution. The characterization data of the adsorbent were analyzed using XRF and FTIR methods. The XRF test r...