This research is dedicated to the role of different amounts hexagonal BN (hBN: 0, 1.5, 3, and 4.5 wt%) on pressureless sinterability ZrB2–25 vol% SiC ceramics. Phenolic resin (5 with a carbon yield ~40 % was incorporated as binder powder mixtures after initial cold pressing, final sintering process performed at 1900 °C for 100 min in vacuum furnace. The as-sintered specimens were characterized ...